Hydrogen Production by Supercritical Water Gasification of Biomass with Homogeneous and Heterogeneous Catalyst外文学习材料.pdfVIP

Hindawi Publishing Corporation Advances in Condensed Matter Physics Volume 2014, Article ID 160565, 9 pages /10.1155/2014/160565 Research Article Hydrogen Production by Supercritical Water Gasification of Biomass with Homogeneous and Heterogeneous Catalyst Hui Jin, Youjun Lu, Liejin Guo, Ximin Zhang, and Aixia Pei State Key Laboratory of Multiphase Flow in Power Engineering, Xi’an Jiaotong University, Xi’an 710049, China Correspondence should be addressed to Liejin Guo; lj-guo@ Received 13 March 2014; Accepted 11 May 2014; Published 16 June 2014 Academic Editor: Shaohua Shen Copyright © 2014 Hui Jin et al. his is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. Biomass gasiication in supercritical water is a clean and eicient way to convert biomass to hydrogen-rich gaseous products. Appropriate catalyst can lower the reaction temperature to guarantee the technological and economic feasibility. his paper selects Ca(OH) , Na CO , K CO , NaOH, KOH, LiOH, and ZnCl as typical homogeneous catalysts and three kinds of Raney-Ni, 2 2 3 2 3 2 dolomite, and olivine as typical heterogeneous catalysts. he catalyst efects are investigated in the process of biomass gasiication in supercritical water with the temperature of 400∘ C, pressure of 22 ∼ 24 MPa, and residence time of 20 min. he experimental results show that Raney-Ni has the best hydrogen selectivity and hydrogen yield. he mixture of NaOH with Raney-Ni was investigated in order to research the synergistic efect of diferent catalysts. he experimental results show that Raney-Ni and NaOH have a