天津不同气团来向PM25中组分和污染源贡献的季节变化.pdf

中国环境科学 2018,38(7) ：2406~2414 China Environmental Science 天津不同气团来向 PM2.5 中组分和污染源贡献的季节变化 * 史旭荣,温 杰, 田瑛泽 ,史国良,张裕芬,冯银厂 (南开大学环境科学与工程学院, 国家环境保护城市空气颗粒物污染防 治重点实验室,天津 300071) 摘要：利用基于新型多点位三维受体模型和后轨迹所构建的来向解析技术(SDA),探讨了天津市内陆和近海点位的不同季节不同来向气团载带的颗粒 3 物浓度、组分和源分担率特征,并定量计算了不同来向污染源对受体点位的贡献大小.整体上,渤海来向的气团相对清洁(97.1µg/m ),气团占比较大 3 (23.7%); 内蒙-河北-北京-天津来向气团载带的 PM2.5 浓度高(197µg/m ),但气团占比小( 内陆点位春冬季分别为 12.5%,11.9%,近海点位春冬季分别为 8.6%,10.7%),对 PM2.5 的综合影响较小.近海点位春夏秋冬季对 PM2.5 分担率最大的污染源分别为:SSW 来向地壳源(12.8%)、SE 来向硫酸盐+SOC(二次 有机碳)(9.8%) 、WSW 来向燃煤源(10.3%)、WNW 来向硫酸盐+SOC(12.1%). 内陆点位分别为 SSW 来向地壳源(14.5%)、S 来向硫酸盐+SOC(13.5%) 、 SSW 来向机动车源(8.9%)、WNW 来向硫酸盐+SOC(9.5%). 关键词：多点位三维模型；污染源来向解析技术；后向轨迹；PM2.5 中图分类号：X513 文献标识码：A 文章编号：1000-6923(2018)07-2406-09 Seasonal patterns of PM2.5 sources and chemical composition from different air mass directions in Tianjin. SHI Xu-rong, WEN * Jie, TIAN Ying-ze , SHI Guo-liang, ZHANG Yu-fen, FENG Yin-chang (State Environmental Protection Key Laboratory of Urban Ambient Air Particulate Matter Pollution Prevention and Control, College of Environmental Science and Engineering, Nankai University, Tianjin 300071, China). China Environmental Science, 2018,38(7)：2406~2414 Abstract ：PM2.5 samples were collected simultaneously at an inland and coastal sites during four seasons in Tianjin, China. A three-way receptor model and HYSPLIT model were utilized to investigate the sources of PM2.5 at two sites, and qualitatively determine the major air mass origins, and then the source directional apportionment (SDA) was applied to quantify