有色金属冶炼部分.doc

doi：10.3969/j.issn.1007-7545.2019.04 doi：10.3969/j.issn.1007-7545.2019.04.012 蔡创开，郭金溢，熊明，苏秀珠 （紫金矿业集团股份有限公司，低品位难处理黄金资源综合利用国家重点实验室，福建 上杭 364200） 摘要：某高砷高铜金精矿含砷高达9.42%，采用加压氧化—氰化工艺处理，铜、金、银浸出率分别为96%~97%、99%、78%，加压氧化过程80%以上的砷固化在氧化渣中。同时开展了铜萃取、萃余液处理、毒性浸出等工艺单元试验，打通整体流程。毒性浸出试验表明，氰化渣、中和渣毒性浸出液中的重金属、砷浓度达标。采用加压氧化工艺处理高砷高铜金精矿是可行的。 关键词：含铜砷难处理金矿；加压氧化；综合回收 中图分类号：TF831 文献标志码：A 文章编号：1007-7545（2019）04-0000-00 Study on Comprehensive Recovery of Gold, Silver and Copper from High-arsenic and High-copper Bearing Gold Concentrate CAI Chuang-kai, GUO Jin-yi, XIONG Ming, SU Xiu-zhu （State Key Laboratory of Comprehensive Utilization of Low-Grade Refractory Gold Ores, Zijin Mining Group Co., Ltd., Shanghang 364200, Fujian, China） Abstract：High-arsenic and high-copper bearing gold concentrate containing 9.42% arsenic was treated by pressurization oxidation-cyanidation. Leaching rates of copper, gold and silver are 96%~97%, 99% and 78%, respectively. More than 80% of arsenic solidifies exist in oxidizing slag. At the same time, copper-extraction, raffinate treatment, toxic leaching and other process unit tests were performed. Copper extraction, raffinate treatment, and toxic leaching test were conducted. The toxic leaching test shows that concentration of heavy metals and arsenic in toxic leaching solution of cyanidation slag and neutralization slag is lower than that of standard value. It is feasible to treat high-arsenic and high-copper bearing gold concentrate by pressurization oxidation process. Key words：copper and arsenic bearing refractory gold concentrate; pressure oxidation; comprehensive recovery 我国难处理金矿占比较大，在已探明的黄金储量中30%的金精矿为难处理金矿[1-2]。含铜、含砷难处理矿石是典型的难处理金矿类型，铜、砷矿物在氰化过程中会消耗大量的氰化钠，砷矿物如毒砂还会包裹金颗粒，从而造成常规氰化药剂消耗量大，且金浸出率低[3-5]。 某矿山浮选的金精矿含金~25 g/t、铜5%~8%、砷7%~9%，为高铜、高砷的多重难处理金精矿。该矿在选矿上无法实现分选，混合浮选后的精矿对金精矿来说含铜太高，当铜精矿铜又太低，只能在冶炼工艺上实现金铜分离。由于含砷过高，焙烧预氧化工艺污染严重、砷处理成本高，且金铜回收率不佳，所以考虑采用湿法手段处理。加压氧化由于氧化完全，金铜分离彻底，砷可在加压氧化过程中形成稳定的砷酸铁沉淀而不污染环境，处理该类型金精矿有独特优势[6-10]。因此，本文以某高铜高砷金精矿为对象，进行了加压氧化工艺的整体流程试验，考察工艺可行性。 1试验原料 金精矿样