电化学研究方法课件-北京大学邵元华教授第三部分2.ppt

(a) r= 12 μm (b) r= 3 μm. Planar structure (a) and 3D structure (b) of a new type of crown ether Cyclic voltammogram with scan rate of 10mV/s for a 14?m-radius micropipette electrode with 100 mM NaCl in aqueous phase and 10mM TBATPB in organic phase Alkali metal ions transfer across the water/DCE interface Facilitated by DB18C6 Ion radius (r), formal transfer potential of relevant alkali metal ions and the association constants of complex (M-DB18C6)+ in DCE phase 冰/有机相溶液界面研究示意图 应用常规三电极装置(恒电势仪)研究电荷在液/液界 面上的转移反应实验装置图 Aqueous phase Effect of the concentration Ratio of the redox couple