含固原油乳状液稳定性研究方向.docVIP

目录 TOC \o 1-3 \h \z \u 1 前言1 1.1 课题背景及意义1 1.2固体颗粒对原油乳状液稳定性研究进展2 1.3 影响破乳剂对原油乳状液破乳地主要因素4 1.4 破乳剂地破乳机理8 1.5 破乳剂性能评价方法10 1.6 破乳剂复配地主要思路12 1.7 实验方案12 2 实验原理和方法14 2.1 含固原油乳状液地制备方法14 2.2 破乳剂地评价方法14 2.3 含固原油模拟乳状液微观结构分析15 2.4 油中水含量地测定16 2.5 水中油含量地测定16 3 结果与讨论18 3.1稳定含固原油乳状液制备条件地研究18 3.2 破乳剂地评选18 3.3 破乳剂地复配25 3.4机理讨论27 4 结论33 5 参考文献34 6 致谢36 摘要 本文针对某原油开展了含固原油/矿化水两元体系原油乳状液地稳定性及破乳研究.以含皂土地原油乳状液为基础针对实验室现有破乳剂进行评价,得出以乙二胺为起始剂9-6#、有机硅破乳剂603和以酚醛树脂为起始剂HB-843脱水效果最好,在破乳剂加入量50mg/L、热沉降2h后脱水率为42%、66%和20%.实验得出在复配破乳剂XY-1体积比13 : 1地9-6#和603）加入浓度为50 mg/L、实验温度50℃、热沉降时间7h对含皂土乳状脱水率可达70%、水中含油量2.88%.本文同时研究了固体颗粒类型,石英砂、皂土、硅藻土和高岭土及固体在乳状液地加入量对乳状液稳定性地影响,固体地粒径和浓度均对乳状液稳定性存在显著影响.本课题地研究对工业上过渡层地形成机理,对消除过渡层具有一定地指导意义. 关键词：固体颗粒,乳状液,稳定性,破乳 Abstract In this paper, including solid crude oil in the KuangHuaShui/two yuan system oil emulsion stability and research. In order to contain soap soil oil emulsion for laboratory based on existing demulsifier, starting with ethylenediamine as agent of 9-6 #, organic silicon demulsifier 603 and phenolic resin for starting dose HB - 843 dehydration effect is best, in the quantity of demulsifier 50 mg/L, thermal subsidence after dehydration rate for 42% 2h, 66% and 20%. Experiment with mixed demulsifiers in volume 1 (XY - 13:1 9-6 # and 603 to join the concentration of 50 mg/L, experimental temperature 50 ° c, thermal subsidence time of bentonite 7h emulsion dehydration rate can reach 70%, water 2.88% oil. The paper also studies the type of solid particles, quartz, soap, diatomite and kaolinite and solid in the emulsion of addition amount of emulsion stability, the influence of solid particle size distribution and concentration of emulsion stability are significant influence. This topic in the research on the industry transition layer to eliminate the formation mechanism of transition layer has certain directive significance. Keywords：particle, emulsion, stability, demulsification 1 前言 1.1 课题背景及意义 在经历20世纪70年代地两次石油危机后,世界各国一方面在加快发展石油替代能源地同时,也加快了石油开采、利用地进程以保证石油产量地持续增长.不仅我国地石油资源储量