焙烧条件对于铁的氧化率的影响.doc

基金项目： 基金项目：国家自然科学基金资助项目 作者简介：吴继平（1988- ），男，硕士研究生，从事湿法冶金与稀土资源回收利用方向研究，E-mail:wujipingjxust@163.com. 通信作者：邓庚凤（1971- ），女，博士，教授，主要从事湿法冶金及稀土功能材料的制备方面研究，E-mail:gfdeng26@126.com. 从钕铁硼废料中提取稀土工艺研究 吴继平，邓庚凤，邓亮亮，林程星，潘贤斌 （江西理工大学冶金与化学工程学院，江西 赣州 341000） 摘要：采用氧化焙烧-盐酸分解法，研究从钕铁硼废料中提取稀土的工艺条件，探讨了焙烧温度和时间对铁的氧化率的影响，在浸出过程中考察了盐酸浓度、反应时间、反应温度以及液固比对稀土浸出率的影响，并分析了pH值和陈化时间对浸出液除杂效果的影响.结果表明：在700 ℃焙烧1.5 h，铁的氧化率最高，铁基本完全氧化成三价铁，在最佳浸出条件下稀土浸出率高达到99.33 %，浸出液中和除杂时，调节pH值为3.5，陈化时间大于2 h，料液中非稀土杂质含量低，特别是铁仅为0.0014 g/L，浸出液完全达到稀土萃取的要求. 关键词：钕铁硼废料；稀土回收；氧化焙烧；盐酸分解；浸出工艺 Study on Rare Earth Recovery from NdFeB magnet scrap WU Ji-ping ,DENG Geng-feng, DENG Liang-liang,LIN Cheng-xing, PAN Xian-bing (School of Metallurgical and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 34100, China） Abstract: The rare earth(RE) extraction conditions from Nd-Fe-B magnet scrap were studied by oxidation roasting - hydrochloric acid decomposition.The influence of calcination temperature and time on the iron oxidation rate was discussed in the roasting process . In the leaching process, the effects of hydrochloric acid concentration, reaction time, reaction temperature and liquid to solid ratio on leaching rate of rare earth were investigated too, and the influence of pH and the aging time of the impurity on the leaching liquid were analyzed. The results show that the oxidation rate of iron reaches maximum with calcining at 700 ℃ for 1.5 hours, and iron is completely oxidated to the trivalent iron. The RE leaching rate reaches 99.33 % at the optimum conditions. After change the pH to 3.5 and the aging time to more than 2 hours for neutralization process, little impurities of Cu,Pb,Co and Fe are dissolved in the leaching solution. The Fe content in the leaching solution is only 0.0014 g/L ,the rare earth leaching solution meets the requirements of RE extraction. Key words: Nd-Fe-B magnet waster; rare earth recycling; Oxidation roasting; hydrochloric acid dissolution; extraction technology 0 引言 钕铁硼永磁材