金属有机化学2011.ppt

金属有机化学Organometallics 徐崇福 1. Introduction（引论） 2. Main-Group Organometallics(主族金属有机化合物) 3. Organometallic Compounds of the Transition Elements(过渡元素金属有机化合物) 1. Introduction（引论） 1.1 Historical Development and Current Trends in Organometallic Chemistry (在金属有机化学领域的历史发展和当前趋势) 1760 The cradle(摇篮) of organometallic chemistry is a Paris military pharmacy(制药厂). It is there Cadet(军校学员) works on sympathetic inks（隐显墨水）based on cobalt salts. For their preparation, cobalt mineral which contain arsenic(砷) was used. As2O3 + 4CH3COOK ? “Cadet’s Fuming liquid”（军学生发烟液体） Contains cacodyloxide (卡可基氧化物) [(C