聚天冬氨酸强化植物修复重金属污染土壤的研究-广东化妆品科学.pdfVIP

中国农学通报 2013,29(29): 151-156 Chinese Agricultural Science Bulletin 聚天冬氨酸强化植物修复重金属污染土壤的研究 张 鑫，史璐皎，刘晓云，张 涵，李玲慧，谭天伟，曹 辉 （北京化工大学，北京100029） 摘 要：为了探究PASP 作为螯合剂在植物修复过程中的强化作用，采用土柱淋滤实验，研究不同浓度的 聚天冬氨酸(PASP)对重金属铅(Pb)、镉(Cd)的活化能力（加入淋出量和空白对比）。结果表明，在一定浓 度范围内，PASP 对Pb 和Cd 的活化能力随PASP 浓度的增加而增加。在盆栽模拟实验中发现，PASP 对 玉米修复重金属污染土壤有明显的强化作用。施用11 g/L PASP 的玉米株高为114.4 cm ，大于施加 EDTA 的植株(110.9 cm)。确定了PASP 的最佳施用浓度为3 g/L 和7 g/L ，吸收重金属量分别为Pb 114.829 μg 和84.662 μg、Cd 54.447 μg 和66.915 μg ，与EDTA 相比对Cd 的吸收量提高约10倍，对Pb 的吸 收量提高约3 倍。进一步用水合肼和乙醇胺对PASP 进行衍生化，淋洗实验证明用乙醇胺改性的PASP 对重金属的活化效果得以提高，为修复被重金属污染的土壤提供了一种较好的络合剂。 关键词：聚天冬氨酸；植物修复；重金属污染土壤；铅；镉 中图分类号：S19 文献标志码：A 论文编号：2012-3947 The Research of Enhancing Phytoremediation of Heavy Metals Contaminated Soil with PASP Zhang Xin, Shi Lujiao, Liu Xiaoyun, Zhang Han, Li Linghui, Tan Tianwei, Cao Hui (BeijingUniversityofChemicalTechnology, Beijing 100029) Abstract: In order to explore the enhancing abilities of PASP during phytoremediation, laboratory simulations of soil columns were designed to research the activated ability of different concentration of polyaspartic acid (PASP) on heavy metal lead (Pb) and cadmium (Cd) (joining leaching quantity and blank contrast). The experiments showed that, in the concentration range, PASP ’s activated ability on heavy metals increased with the increasing of PASP ’s concentration. With the pot experiments, it was seen that PASP could significantly enhance the effect on corn remediation of heavy metals contaminated soil. The heights of corn that applied 11 g/L PASP was 114.4 cm, which was better than the corn that applied EDTA (110.9 cm). It was proved that the best concentration of PASP application was 3 g/L