芦苇浆造纸黑液资源化处理新工艺.docxVIP

Vol.22 No.7July 2012文章编号 Vol.22 No.7 July 2012 文章编号：1004-0609(2012)07-2109-07 芦苇浆造纸黑液资源化处理新工艺 杨卫春 1, 2，尤翔宇 1，王云燕 1, 2，赵 静 1, 3，柴立元 1, 2，舒余德 1 (1. 中南大学 冶金科学与工程学院，长沙 410017； 2. 中南大学 国家重金属污染防治工程技术研究中心，长沙 410017； 3. 江苏交通科学研究院股份有限公司，南京 210017) 摘 要：针对芦苇浆造纸产生的浓缩黑液的特点，提出了黑液脱硅—酸析回收木质素—三维电极电解—苛化回收 NaOH—出水返回生产的工艺流程。采用 Ca(OH)2 沉淀法去除黑液中的 SiO2，黑液中硅含量由 6.68 g/L 降至 0.12 g/L，脱硅率为 98.20%；黑液脱硅后加入 H2SO4 去除 COD 并回收木质素，CODCr 由 220.648 g/L 降至 54.179 g/L 左右，脱除率达到 75.45%，每 100 mL 黑液可回收 8.5 g 木质素。FTIR、SEM 和 EDX 的分析结果表明：酸析木 质素结构以紫丁香基和对羟基的单体结构为主；采用三维电极反应器处理酸析液，残余 CODCr 为 36.761 g/L，TOC 的去除率达 35.57%；利用苛化法回收残碱，用于制浆蒸煮工段，实现废水的零排放。苛化后的黑液中有效碱浓度 为 8.30 g/L，苛化度为 78.60%，苛化后 TOC 降低了 9.99%，残余 CODCr 浓度为 33.085 g/L，可返回生产，实现了 资源的综合回收与利用。 关键词：造纸黑液；脱硅；酸析；三维电极；木质素 中图分类号：X703.1; X793 文献标志码：A Novel technology of resource recovery from reed black liquor YANG Wei-chun1, 2, YOU Xiang-yu1, WANG Yun-yan1, 2, ZHAO Jing1, 3, CHAI Li-yuan1, 2, SHU Yu-de1 (1. School of Metallurgical Science and Engineering, Central South University, Changsha 410017, China; 2. National Engineering Research Center for Pollution Control of Heavy Metals, Central South University, Changsha 410017, China; 3. Jiangsu Transportation Research Institute Co., Ltd., Nanjing 210017, China) Abstract: A novel process was proposed to treat reed black liquor: desilication—acidification—three-dimensional electrolysis—causticization—reuse in pulp making. The precipitation method was used to remove silicon by adding Ca(OH)2. The residual concentration of silicon decreases from 6.68 g/L to 0.12 g/L and the removal rate of silicon is maintained at 98.2%. Lignin was recovered by acidulation-precipitation after the addition of sulfuric acid. The residual concentration of CODCr can be reduced from 220.648 g/L to 54.179 g/L and its removal rate is maintained at 75.45%. 8.5 g lignin was recovered from 100 mL black liquor. Based on the analysis of FTIR, EDX and SEM, it is found that the structure of lignin consists mainly of syringyl monomers and hyd