硫化与再生过程对Pt2fγ-Al2O3催化剂NO氧化活性的影响分析.pdfVIP

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硫化与再生过程对Pt2fγ-Al2O3催化剂NO氧化活性的影响分析.pdf

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Abstract Because of the potential crisis of Pt/γ-Al O catalysts being poisoned by S-containing 2 3 impurities in diesel exhausts, it is important to better understand the deactivation of SO2 and its regeneration effects on Pt/γ-Al O catalysts. In this study, these effects induced 2 3 by SO on Pt/γ-Al O were studied as a function of SO exposure time, and NO 2 2 3 2 oxidation activity was investigated for different treated Pt/γ-Al O catalysts. The results 2 3 show that the SO2 exposure period seriously affects the catalytic ability, especially after a long period for the sulfation process. TEM, CO-DRIFTS, TGA, and STEM-EDS elemental mapping results show that Pt physical and chemical states, and SOx species are considered to be essential parameters in the SOx effects on the catalysts. It is found that partial regeneration in the samples with different SO2 exposure times is primarily caused by an un-recoverable deactivation of edge and kinked Pt atoms during the sulfation process. Moreover, the mechanism of SOx loading and its elimination through NO oxidation process, investigated by in situ DRIFTS, provides further cognizance on SO species and their removal. The mechanism reveals a special intermediate SO x x