阴非离子分散剂协同作用对分散染料分散稳定性能的影响.docVIP

摘要 PAGE PAGE I PAGE PAGE I 摘要 摘 要 超细分散染料是涤纶织物喷墨印花分散墨水的主要组分，其品质决定了喷墨印花墨水的稳定性和喷射性．商品化的分散染料颗粒较大，分布较粗，应用时需要对其进行超细化加工． 分散剂是影响超细分散染料分散稳定性能的主要材料，单一分散剂分散效率低，稳定性较差，造成生产成本增高.本文采用阴/非离子分散剂复配，通过研磨分散法制备了超细分散染料红60，研究了阴/非离子分散剂的协同作用下对分散染料分散和稳定性能的影响，优化了超细分散染料的制备工艺.在优化工艺条件的基础上，重点研究了超细分散染料粒径及其分布、Zeta电位、分布形态等性能，探讨了协同作用对其分散速度、稳定性和吸附量的影响. 研究结果表明，采用单一分散剂木质素磺酸钠制备超细分散染料的粒径为230nm，而采用木质素磺酸钠与TMN-6复配的分散剂，在相同条件下制备超细分散染料的粒径为174nm.性能对比发现，采用阴/非离子分散剂复配制备的超细分散染料对温度的稳定性较单一分散剂木质素磺酸钠分散剂提高了6%，离心稳定性提高了4%，复配后制备的超细分散染料的粒径分布更加均匀．进一步优化超细分散染料的制备工艺为分散剂含量80%，研磨时间3h，染料固含量15%． 关键词：阴/非离子分散剂；分散染料；协同作用；分散稳定 Abstract Abstract PAGE ii Abstract ABSTRACT Ultra-fine disperse dye is a major component of ink-jet printing inks for polyester fabrics.Its quality determines the stability and the ink-jetting performance of ink-jet printing inks.Because commercial disperse dyes particles is larger, and the distribution is coarser, so need the refinement processing when the inks are formulated. Dispersant is the key factor that affect dispersion stability of ultra-fine disperse dye,the dispersion efficiency is low when use one dispersant, and the stability is poor, which is unfavorable for energy saving and emission reduction of development needs of society.The paper use the mixture of anionic dispersant and non-ionic dispersant, ultra-fine disperse dye red 60 is prepared by milling method, and then investigated the influence of dispersion stability of disperse dye on synergistic effect of the mixture of anionic-nonionic dispersant, optimized the preparation methods of ultra-fine disperse dye of dosage of anionic-nonionic dispersant, dye solid content and milling time. On the basis of optimum technology conditions,and studied the performance of ultra-fine disperse dye on partical size and particle size distribution ,Zeta potential,distribution and present forms,the influence of synergistic effect on dispersion speed,stability and absorption capacity is discussed. The results showed that the particle size of disperse