硫化锌微米球的合成及其光催化性能-硅酸盐学报.pdf

第43 卷第1 期 硅 酸 盐 学 报 Vol. 43 ，No. 1 2 0 1 5 年 1 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY January ，2015 DOI ：10.14062/j.issn.0454-5648.2015.01.20 硫化锌微米球的合成及其光催化性能 马晓品，景志红，丰 奇，陈 莹，耿小红 ( 曲阜师范大学化学与化工学院，山东 曲阜 273165) 摘 要：以硫代乙酰胺为硫源，采用传统的水热法和改进的均匀沉淀–水热法制备了ZnS 微米球。对制备的样品进行了表征； 以紫外灯为光源，染料罗丹明B 、甲基橙、亚甲基蓝为目标降解物，考察了两种方法制备的ZnS 微米球的光催化活性。结果 表明：改进的均匀沉淀–水热法条件温和，制备的ZnS 微米球形貌规则、尺寸均一。沉淀–水热法制备的样品具有较高的光催 化活性，在紫外光照射170min 后对罗丹明B 的降解率达到98% ；光照130min 后对甲基橙的降解率达到95% ；光照110min 后，对亚甲基蓝的降解率达到98% 。其光催化性能明显优于传统水热法制备的ZnS 微米球。 关键词：硫化锌；水热法；均匀沉淀–水热法；光催化性能 中图分类号：O614.2 文献标志码：A 文章编号：0454–5648(2015)01–0121–06 网络出版时间：2014−12−18 15:11:00 网络出版地址：/kcms/doi/10.14062/j.issn.0454-5648.2015.01.20.html Synthesis and Photocatalytic Properties of Zinc Sulfide Microspheres MA Xiaopin , JING Zhihong, FENG Qi, CHEN Ying, GENG Xiaohong (College of Chemistry and Chemical Engineering, Qufu Normal University, Qufu 273165, Shandong, China) Abstract: Zinc sulfide (ZnS) microspheres were synthesized via a conventional hydrothermal method and a modified homogeneous precipitation–hydrothermal method with thioacetamide as a sulfur source, respectively. The prepared ZnS microspheres samples were characterized. The photocatalytic properties of the ZnS microspheres were evaluated via photocatalytic degradation of rhodamine-B, methyl orange and methylene blue under ultraviolet (UV) light. The results show that the ZnS microspheres with the regular shape and uniform size synthesized by the precipitation–hydrothermal method can be obtained under a mild reaction condition. Moreover, the ZnS microspheres sample synthesized by the precipitation–hydrothermal method has a greater phot