钙钛矿结构外延结果 Argonne.pptVIP

* * * * * * * * Whether the atoms have this in-plane mobility or not might provide an explanation for the very different ground states found experimentally in related heterostructures. Using the same experimental set up, growth and characterization method, etc. The Geneva group have observed how high-quality ultrathin film of PbTiO3 grown on Nb-doped SrTiO3 remain in a monodomain configuration while it form domains if the substrate is replaced by lanthanum, strontium manganate. * Ideally, closure domains do not produce any polarization charge since the normal component of the polarization is preserved across the domain wall. Therefore a vanishing depolarizing field and a constant electrostatic potential is expected. However, an analysis of the electrostatic potential reveals the existence of a residual depolarizing field along z, that might be responsible for the decreasing of the polarization inside the domains, and a large field along [100] in the domains of closure right at the interface between the electrode and the ferroelectric. This field might be the preferential points of pinning for charged defects. And it is well known that the defects inhibit the motion of the domain walls. Thus, this domains of closure might play a role on the fatigue of the sample, the most important device failure in ferroelectric ultrathin devices. * * * * * * * * * ELECTROSTATIC 1: * * * * * * * * * * * * * * * * * * * * * Second: as it was already shown in bulk, Ba centered domain walls are more stable than Ti centered domain walls. * * * * * * * Rochelle salt Different families of ferroelectric materials Hydrogen bonded materials First serie of isomorphous ferroelectric crystals KH2PO4 (KDP), 16 atoms/cell Arrangements of hydrogens ? different orientations (H2PO4)- Rochelle salt Different families of ferroelectric materials Hydrogen bonded materials Copolymers Long chains of C with elements of different electronegativity Rochelle salt Different families of ferroelectri