第7章气体动理论.ppt

Idea：A Theory for 1023 Particles In classical theory a particle’s next move depends upon (equated to) its position, velocity and force acting on it Trying to solve such equations for a mole of gas with 1023 particles each with x,y,z coordinates and different speeds is almost impossible Ideal vs. Non-Ideal Gases Non-Ideal Gas Violates(违背) assumptions Volume of molecules Attractive forces of molecules The degrees of freedom of polyatomic molecule is six, and 多原子分子 and the contribution of rotation motion is 小结 两个结论： 一个概念：自由度 一个假设：能量按自由度均分 表述 在温度为T 的平衡态下，物质(汽 液 固)分子每个自由度具有相同的平均动能，其值为 例题：有A、B两容