可聚合超支化大分子光引发剂的合成与研究.doc

PAGE PAGE 9 可聚合超支化大分子光引发剂的合成与研究 摘要 紫外光引发剂是紫外光固化过程中的重要组分，对体系固化速度和固化程度有重要影响。本文旨在克服超支化大分子光引发剂和可聚合光引发剂的光解残留、溶解性较差以及残留光引发剂的挥发问题，将可聚合结构引入到超支化大分子结构上，成功的合成了一种可聚合超支化大分子光引发剂。 以二乙醇胺和马来酸酐为原料，反应合成一种AB2型单体MA-DEA，确定最佳合成条件为：以DMF作为溶剂，反应温度为25℃，n（马来酸酐）:n（二乙醇胺）=1:1，反应时间为2h。以三羟甲基丙烷作核，与MA-DEA进行酯化反应，采用一步法成功的合成出代端羟基超支化聚胺酯：MDT, MDT的最佳合成条件为：对甲苯磺酸用量为总体系质量的0.2g，反应温度为110℃，反应时间为5h。用马来酸酐对两代端羟基超支化聚胺酯进行改性，对甲苯磺酸为总体系质量的0.2g，反应温度为130℃，反应时间为5h。 用1173对两代端羟基超支化聚胺酯进行封端改性，反应温度为120℃,反应时间为8h。 通过FT-IR对MDTM-1173结构和性能进行了表征，结果表明成功的合成了目标产物。 关键字：可聚合，超支化，大分子光引发剂，紫外光固化 SYNTHESISAND STUDY OF POLYMERISABLE HYPERBRANCHED MACROMOLECULAR PHOTOINITIATORS ABSTRACT Ultraviolet initiator is an important component of the uv-curable process,it have important influence for system solidifying velocity and curing degree. From this paper we want to overcome hyperbranched macromolecular photoinitiator and polymerisable photoinitiators of photodissociation residue, solubility poorer and remain photoinitiators volatile problem. successfully synthesized a polymerisable hyperbranched macromolecular initiator by macromolecular structure is introduced to hyperbranched polymer structure. An AB2 type monomer MA-DEA has been synthesized by Diethanolamine and Methyl acrylate . the best synthesis condition for DMF as solvent methacrylate,n(maleic anhydride): n(Diethanolamine)=1:1, reaction temperature for25℃and reaction time for 2h.With TMP and MA-DEA, using one-step successfully synthesized one generations of the hydroxyl hyperbranched poly amino ester:MDT, the best synthesis condition of the MDT for P-toluene sulfonic acid dosage for total system quality 0.2g, reaction temperature for 110 ℃, n (MA-DEA) : n (TMP) = 3:1, the reaction time for 5h with maleic anhydride for two generations of the hydroxyl hyperbranched poly amino ester modified. P-toluene sulfonic acid dosage for