桉树枝干微波热解实验及研究生物质能源论文.docVIP

桉树枝干的微波热解实验及研究 摘 要 生物质是一种可再生资源，将生物质转化为高品位能源具有重要的意义。生物质热裂解是一种重要的热化学转化技术，通过对生物质的裂解曲线研究，可以为生物质热化学转化利用提供一定的理论基础本实验是以桉树枝干为原料，采用大功率微波设备及温度采集系统考察了桉树裂解特性，根据其裂解特性初步解释了其裂解机理。本实验首先对大功率微波设备进行了调试，数据表明单个磁控管在较大空间的微波辐射由于衰减及互相干扰等因素，微波效率在整个微波空间不均匀且不稳定而多个磁控管的不规律设置导致在任意两个或两个以上磁控管共同工作时干扰相当严重。因此通过各个点的重复性实验选取较为稳定并且效率较为高的点作为生物质热解的实验点即炉膛中间高约156mm的点。实验取物料重量分别为15g、20g、30g、45g、60g，载气为氮气，催化剂为氧化钙，气氛流速为1000ml/min，分别进行不同重量和不同比例CaO的对比实验。实验表明不同重量物料的热解曲线差异不大即验证了微波加热不受物料质量或体积的影响。但重量相差太大，散热、吸收微波能力等因素就会大大影响热解升温曲线的走势。而由于CaO会延缓物料的热解，使物料需要更多的时间裂解，从某种程度上不利于生物质的裂解。但CaO对于生物质裂解抑制与催化的共同作用使得CaO可作为一种平缓剂添加进热解物料中，本实验结果表明添加比例为5％CaO的物料热解过程最理想，并且热电偶对热解影响非常大。 关键词：生物质；桉树；裂解；微波  Abstract Biomass is a kind of renewable resources, it has the vital significance to convert biomass into high grade energy. Thermal cracking of biomass is a kind of important thermal and chemical conversion technologies, through the research of cracking curve of biomass, it can provide thermal chemical conversion with certain theoretical foundation. This experiment use limb of eucalypt as raw material, using high power microwave equipment and temperature gathering system investigate its cracking characteristics, and according to the heating curves I carry out the research of cracking characteristics of eucalyptus. Finally, according to its cracking characteristics preliminarily I interpret its cracking mechanism. The experiment of high power microwave equipment first debug, data shows that individual magnetrons in larger space microwave radiation due to attenuation and mutual interference factors in the microwave, microwave efficiency space not uniform and unstable and multiple magnetrons caused the irregular in any set of two or more magnetrons common work interference pretty serious. So through the various points on a relatively stable and repetitive experimental selection is high efficiency of biomass pyrolytic point as 156mm furnace high about that among the point. Experiment respectively take material weight 15g, 20g 30g, 45g, 60g, carri