聚合物分子设计的原理与方法-4-20.ppt

Similar results were obtained with some MAO-activated lanthanidocenes (119–123) (MeCp)2Sm(O-2,6-tBu-4-MeC6H2), Flu2NdCl, Ind2NdCl and Me2Si(Ind)2NdCl. Higher activities and higher molecular weights (Mn = 100,000–620,000 g/mol) were obtained with anionic tetrakis (allyl) complexes (124–125), still with predominant syndiotacticity (but not precisely determined) The yttrium alkyl (C5Me4SiMe2NtBu)Y(-C6H13)(THF) (126) also initiates styrene polymerization with moderate activity after partial THF removal. The obtained PS shows moderate molecular weight (Mn = 24000–61000 g/mo