酸硷中和程序适应性控制之研究.doc

[ 摘要 ] 在本論文中，為了處理非線性且時變的酸鹼中和程序，我們採用一個虛擬多質子酸來模擬進料組成並以修飾之強 酸當量來描述此虛擬多質子酸之有效酸性度。這個多質子酸之質子數目、濃度和平衡常數可不需額外的設備即可 利用最小平方估測技術線上估測獲得。在控制器設計方面，為避免因直接使用酸鹼值定義系統誤差導致失控的結 果，我們將採用線上估測獲得的參數，以反轉滴定函數將酸鹼值線性化，再定義系統誤差並設計控制器，經模擬 結果顯示，本論文提出之運算式可迅速估測未知進料成份種類之參數並提供理想的pH控制。 [ 英文摘要 ] In order to tackle nonlinear and time-varying characteristics in pH neutralization processes, a single fiction polyprotic acid is used to represent the influent stream and the effective acidity of the polyprotic acid is described by the modified strong acid equivalent in this thesis. The unknown total concentration, dissociation constants, and protic number of the fiction polyprotic acid are then estimated by on-line least squared method without any additional equipment. To avoid highly nonlinearity in pH neutralizations, the error of controller is parameterized by the inverse of the titration curve instead of pH values. The computer simulation results show the proposed control algorithms are able to quickly obtain the parameters of the fiction polyproitc acid and provide a good performance for pH control processes. [ 論文目次 ] 中文摘要-----------------------------------------------------i英文摘要-----------------------------------------------------ii誌謝--------------------------------------------------------iii目錄---------------------------------------------------------iv表目錄-------------------------------------------------------vi圖目錄------------------------------------------------------vii第一章 緒論-------------------------------------------------11-1前言----------------------------------------------------11-2文獻回顧------------------------------------------------21-3研究動機與目的------------------------------------------31-4組織章節------------------------------------------------4第二章 酸鹼中和系統-------------------------------------------52-1前言----------------------------------------------------52-2反應系統動態模式----------------------------------------52-3系統模式說明與模擬--------------------------------------72-4結論----------------------