铝基碳化硅复合材料超疏水表面的蚀刻制备及性能表征.pdf

第30 卷 第1 期 腐蚀科学与防护技术腐蚀科学与防护技术 Vol. 30 No. 1 2018 年1 月 CORROSION SCIENCE AND PROTECTION TECHNOLOGY Jan. 2018 铝基碳化硅复合材料超疏水表面的蚀刻制备 及性能表征 张瑞麟 郭钟宁 江树镇 吴 明 罗红平 王 冠 广东工业大学机电工程学院 广州 510006 摘要 通过简单的盐酸溶液蚀刻方法在2024 铝基碳化硅复合材料基体上制备出超疏水表面，电镜观察结果显 示，蚀刻后复合材料中碳化硅颗粒自身作为超疏水结构所必需的微米级结构，而碳化硅微粒上又具有纳米级 颗粒，形成了类似荷叶表面的微米-纳米二级复合结构。结合氟硅烷修饰，获得了接触角高达157.02°，滚动角 5° 的超疏水表面。实验研究了不同蚀刻液浓度和时间对表面疏水性的影响，得到特定条件下的最佳工艺参 数：盐酸溶液浓度15% (质量分数) ，蚀刻时间2 min 。性能测试结果表明，所制超疏水表面具有较好的抗酸碱性 能、稳定性、耐磨性和抗腐蚀性能。 关键词 超疏水表面 铝基碳化硅复合材料 微米-纳米二级复合结构 盐酸蚀刻 中图分类号 TG 172 文章编号 1002-6495(2018)01-0061-06 Preparation of Super-hydrophobic Surface of SiC/2024Al Composite Through Chemical Etching and Its Properties ZHANG Ruilin, GUO Zhongning, JIANG Shuzhen, WU Ming, LUO Hongping, WANG Guan School of Eletromechanical Engineering, Guangdong University of Technology, Guangzhou 510006,China Correspondent: GUO Zhongning, E-mail ：znguo@gdut.edu.cn Supported by National Natural Science Foundation of China and Guangzhou Science and Technology Plan (201604030065, 201604010041) Manuscript received 2017-03-17, in revised form 2017-04-28 ABSTRACT Super- hydrophobic surface of SiC/2024Al composite was prepared firstly via a simple chemical etching method and then finishing with fluoroalkyl silane. The surface morphology of the etched SiC/2024Al composite was characterized by means of FSEM. Results show that after chemical etching, the polished surface of SiC particulates within SiC/2024Al composite becomes a surface with composite structures both in micro- and nano-scales, which was highly simila