酚液化竹材制备酚醛树脂成型物之碳化处理及其性质-中兴大学森林系.pdf

林產工業34(2) ：81~88(研究論文) 81 DOI: 10.6561/FPI.2015.34(2).4 酚液化竹材製備酚醛樹脂成型物之碳化處理及其性質 1 2 陳奕君 李文昭 【摘要】本研究將孟宗竹粉在酚溶劑中以酸（硫酸、鹽酸）為催化劑進行液化處理，所得酚液化竹材與甲醛反應製備 水溶性與醇溶性Resol 型酚醛樹脂（Phenol-formaldehyde resins; PF ）及Novolak 型PF 樹脂，並利用不同合成條件PF 樹脂製作硬化樹脂成型物。由DSC 熱分析結果顯示，以液化竹材為原料所製備三種PF 樹脂成型物與利用化石酚為 原料之PF 樹脂成型物有相似的熱性質。進一步將各不同條件成型物以800°C 之高溫加熱進行碳化處理。由結果得知， 以醇溶性PF 樹脂之成型物有最高收率，其次為Novolak 型PF 樹脂。碳化處理時，採用2°C/min 及5°C/min 兩種升 溫速率比較，升溫速率較快者其碳化產物之收率較高，尺寸收縮率較小。 【關鍵詞】液化竹材、酚醛樹脂、成型物、碳化。 Carbonization and Properties of Moldings Made with Phenol-formaldehyde Resins Prepared from Phenol-liquefied Bamboo Yi-Chun Chen 1 Wen-Jau Lee 2 【Abstract 】In this study, powders of Phyllostachys heterocycla (Moso bamboo) were liquefied in phenol with H SO and HCl 2 4 as catalysts, respectively. The liquefied bamboo was used to prepare water-soluble and alcohol-soluble Resol type phenol-formaldehyde resins (PF) and Novolak type PF resin by reacting with formaldehyde. The moldings of cured resin were manufactured from PF resins that prepared by different synthesis conditions. The experimental result of DSC thermal analysis showed that moldings made with three types of PF resin prepared from liquefied bamboo had the thermal property similar to that made with PF resin prepared with fossil phenol as raw material. Furthermore, moldings that made with different conditions were carbonized at 800°C. The results showed that the molding made with alcohol-soluble Resol type PF resin had the highest yield, followed by Novolak type PF resin. Com