油页岩半焦燃烧特性的研究.docxVIP

2005 年 8 月Proceedings of the C 2005 年 8 月 Proceedings of the CSEE ?2005 Chin.Soc.for Elec.Eng. 文章编号：0258-8013 (2005) 15-0106-05 中图分类号：TK16 文献标识码：A 学科分类号：470?20 油页岩半焦燃烧特性的研究 韩向新，姜秀民，崔志刚，张超群 （上海交通大学 机械与动力工程学院 热能工程研究所，上海市 闵行区 200240） STUDY OF COMBUSTION PERFORMANCE OF OIL SHALE SEMI-COKE HAN Xiang-xin JIANG Xiu-min CUI Zhi-gang ZHANG Chao-qun (Institute of Thermal Energy Engineering, School of Mechanical Engineering, Shanghai Jiaotong University, Minhang District, Shanghai 200240,China) 影响不大。为保证半焦通过循环床炉膛能一次燃尽，建议适 当减小半焦颗粒直径和延长颗粒在炉内的停留时间。最后采 用二元一次线性回归法求出了半焦燃烧动力学参数，计算结 果可供数值仿真和工程设计参考。 ABSTRACT: This paper studied combustion performance of oil shale semi-coke by thermogravimetric analysis method and talked about the effect of distillation degree and temperature rising rate on combustion process. Distillation degree influences the start temperature of mass loss and combustion process of low-temperature stage, but has little effect on combustion of high-temperature stage; TG curves obtained under different temperature rising rates show that lower temperature rising rates are beneficial to burnout of semi-coke, but DTG curves show that rate of mass loss will increase with temperature rising rates; ignition temperature will increase with content of volatile decreasing, but have little relation to temperature rising rates. In order to confirm complete burnout of semi-coke passing once through the furnace of CFB, the author advised reducing the diameter of semi-coke and lengthening the residence time of it in the furnace. At last, combustion kinetic parameters of semi-coke were calculated by binary linear regression and the results may be referred to for emulation calculation and engineering design. 关键词：热能动力工程；油页岩半焦；热分析；干馏度；升 温速率；燃烧特性 1 引言 油页岩是有发展前途的替代能源之一，除直接 燃烧外[1-2]，也是加工炼制液体燃料的重要来源，而 且从中可以提取许多化工产品，甚至是某些产品不 可替代的来源。随着人们对油页岩应用技术研究的 深入[3-5]和循环流化床燃烧技术的发展[6-8]，为油页 岩的高效、经济、洁净利用提供了新的途径。作者 提出了油页岩优化综合利用方案：即油页岩首先炼 油，炼油产生的油页岩半焦废料送入循环流化床燃 烧发电，循环流化床的排渣生产建筑材料。在整个 优化利用