辐照交联法制备锂离子电池用凝胶聚合物电解质及其性能_图文_百.docVIP

[Article] 物理化学学报(Wuli Huaxue Xuebao Acta Phys.鄄Chim.Sin .,2007,23(12:1932-1936 December 10,2007;Published on Web:October 25,2007.? Corresponding author.Email:qilu@;Tel:+8610Fax:+8610 + 2007年动力锂离子电池技术及产业发展国际论坛会议论文 ?Editorial office of Acta Physico ?Chimica Sinica 辐照交联法制备锂离子电池用凝胶聚合物电解质及其性能+ 宋兆爽 其 鲁? 邱景义 马建伟 (北京大学化学与分子工程学院,北京 100871 摘要:采用γ?射线辐照交联法制备了具有网络结构的聚偏氟乙烯?六氟丙烯/新戊二醇二丙烯酸酯(PVDF ?HFP/NPGDA基凝胶聚合物电解质(GPE.考察了不同辐照剂量对凝胶电解质形貌结构、热稳定性和电化学性能的影响以及不同辐照剂量和不同温度下电导率的变化.结果表明,随辐照剂量的增加,凝胶电解质的固化程度提高,电导率下降.电导率随温度的变化符合VTF 方程.当辐照剂量为5kGy 时,制备的凝胶电解质具有较高的离子电导率和电化学稳定窗口,室温下分别为7.8×10-3S ·cm -1和4.7V(vs Li/Li +.以其为电解质制备的LiMn 2O 4|GPE |Li 聚合物锂离子电池具有较好的循环性能.关键词:凝胶态聚合物电解质;γ?射线辐照; 交联网络结构; VTF 方程 中图分类号:O646 Preparation and Characterization of 酌?Ray Irradiated Gel Polymer Electrolyte for Lithium ?Ion Polymer Batteries SONG Zhao ?Shuang QI Lu ?QIU Jing ?Yi MA Jian ?Wei (College of Chemistry and Molecular Engineering,Peking University,Beijing 100871,P.R.China Abstract :The gel polymer electrolyte (GPEbased on PVDF ?HFP and NPGDA network was prepared via γ?ray irradiation method.The structure,thermal stability and electrochemical performace of the GPE effected by irratiation dose were examined.The relationship between ionic conductivity and temperature followed Vogel ?Tamman ?Fulcher (VTFequation,which suggested amorphous regions being dominant in GPE.The GPE irradiated at 5kGy exhibited electrochemical stability up to 4.7V vs Li/Li +and high conductivity of 7.8×10-3S ·cm -1at 25℃.In situ prepared LiMn 2O 4|GPE |Li cells exhibited good cycle performance,which provided a new approach to the fabrication of lithium ?ion polymer batteries (LiPBs. Key Words :Gel polymer electrolyte; γ?ray irradiation;Cross ?linking network;VTF equation 随着电动车和电动工具的发展普及,人们对锂离子电池的性能提出了更高的要求,即能量密度大、 功率高、循环寿命长、安全性好、体积小.显然,第一代液态锂离子电池已经不能满足需求.近年来,新一代聚合物锂离子二次电池已成为锂电池领域的研究热点.聚合物电解质是聚合物锂离子电池的关键组成.而凝胶态聚合物电解质既具有固态聚合物的稳定性、可塑性,又具有液态电解质的高离子导电性,被认为是最有希望应用于锂离子电池中的聚合物电解 质[1].但采用单一的聚合物基体,利用热聚合法获得的凝胶聚合物电解质往往机械强度较差,与电极的相容性不