复合有机污染物在含水层介质表面的吸附性能-中国环境科学.pdf

中国环境科学 2018,38(9) ：3413~3420 China Environmental Science 复合有机污染物在含水层介质表面的吸附性能 李 卉 1*,邓 强 2 (1. 中国地质科学院水文地质环境地质研究所,中国地质调查局地下水污染机理与修复重点实验 ,河北 石家庄 050061 ；2.河北地质大学水资源与环境学院,河北 石家庄 050031) 摘要：为明确氯代烃芳香烃类复合污染物在含水层介质上的吸附特性,选取甲苯、苯 1,2-二氯丙烷,1,2,3-三氯丙烷(TCP)作为典型污染物开展吸附试 验,结果表明吸附过程符合 Henry 线性模型,分配系数 Kp 值分别为 0.38,0.41,0.73,1.00kg/L,污染物在细砂上的吸附强度顺序为甲苯苯1,2-二氯丙烷 TCP;竞争吸附试验结果表明,苯可以明显促进甲苯在细砂介质上的吸附,而甲苯抑制了苯的吸附;1,2-二氯丙烷抑制 TCP 在细砂介质上的吸附,而 TCP 对 1,2-二氯丙烷的吸附影响并不明显.TCP 在含水层介质上的吸附量随甲苯浓度增加而增大;当甲苯初始浓度2mg/L 时,TCP 对于甲苯在含水层介质上 的吸附起促进作用,当甲苯的初始浓度≥2mg/L 时,TCP 对于其在含水层介质上的吸附起抑制作用. 关键词：有机物；复合污染；含水层；竞争吸附；1,2,3-三氯丙烷 中图分类号：X523 文献标识码：A 文章编号：1000-6923(2018)09-3413-08 Adsorption characteristic of organic combined pollutants on the surface of groundwater aquifer. LI Hui1*, DENG Qiang2 (1.Key Laboratory of Groundwater Contamination Remediation, China Geological Survey, The Institute of Hydrogeology and Environmental Geology, Chinese Academy of Geological Science, Shijiazhuang 050061, China ；2.College of Water Resource and Environment, Hebei Geology University, Shijiazhuang 050031, China). China Environmental Science, 2018,38(9)：3413~3420 Abstract ：To definite the adsorption characteristics of chlorohydrocarbon and aromatic hydrocarbon combined pollutants in groundwater aquifer, adsorption tests were carried out with toluene, benzene, 1,2-dichloropropane, 1,2,3-chemical propane (TCP) as typical pollutants. The results showed that the adsorption process could be described by linear model of Henry with distribution coefficient (Kp) of 0.38, 0.41, 0.73 and 1.00kg/L, respectively, which indicated that the order of adsorption strength of the pollutants is toluenebenzene1, 2-dichloropropaneTCP. Furthermore, it was