火焰原子吸收法测定钠元素分析条件的优化.pdf

8 5 Vol. 8 No. 5 2017 5 Journal of Food Safety and Quality May. , 2017 * 欧阳超 , 陈均洪, 朱智惠, 刘玉凤, 李慕琪 (, 519040) 摘 要: 目的 方法 /, 结果 : 4.0 mA; 140 kPa; /1:7; 0.4 nm; 1.0~5.0 mg/L (r=0.9996), (RSD=0.54%), 1.03.0 6.0 mg/L , 98.09%101.63%99.49%结论 , , , 关键词: ; ; ; Optimization of analytical conditions of determination of sodium by flame atomic absorption spectrometry * OUYANG Chao , CHEN Jun-Hong, ZHU Zhi-Hui, LIU Yu-Feng, LI Mu-Qi (By-Health Coco., ltdLtd , Zhuhai 519040, China) ABSTRACT: Objective To explore the optimum working conditions for the determination of sodium element by flame atomic absorption spectrometry. Methods The orthogonal test was conducted using instrument lamp, slit width, compressed air flow, and fuel gas/oxidant gas ratio as considering parameters, to determine the best measurement conditions. Results The optimum working conditions were as follows: element lamp current was 4.0 mA, compressed air flow was 140 kPa, fuel gas/oxidant gas ratio was 1:7, slit width was 0.4 nm. Under the optimum working solution, sodium element had a good linear relationship in the range of 1.0~5.0 mg/L(r=0.9996) with good precision (RSD=0.54%). The recoveries of sodium element spiked at 1.0, 3.0 and 6.00 mg/L were 98.09%, 101.63% and 99.49%, respectively. Conclusion The analysis and optimization solve the problem of high-concentration standard curve downward b