富铟锌铁渣中锌和铟的浸出与铁的同步还原（.docVIP

富铟锌铁渣中锌和铟的浸出与铁的同步还原收稿日期：2015-1 收稿日期：2015-11-3 基金项目：国家自然科学基金资助项目 作者简介：朱北平(1968-)，女，汉族，湖南浏阳人，高级工程师，主要从事湿法炼锌研究 通讯作者：邓志敢(1983-)，男，汉族，河北肃宁人，讲师，主要研究方向为湿法冶金. dengzhigan83@163.com 朱北平1，邓志敢2*，张帆2，魏昶2，李存兄2 （1. 云南华联锌铟股份有限公司，文山 663701； 2. 昆明理工大学 冶金与能源工程学院，昆明 650093） 摘要：我国锌资源储量丰富，其含锌矿物中有很大一部分以高铁闪锌矿的形式存在，并且在这些高铁闪锌矿其中含有丰富的铟资源。为了综合回收高铁闪锌矿湿法炼锌过程富集于中浸渣中的有价金属，开展了中浸渣和锌精矿的还原酸浸实验研究，其主要目的是利用硫酸浸出中性浸出渣中以铁酸盐形式残留的锌和铟，同时利用锌精矿将溶液中的三价铁还原为二价铁，实现锌精矿中锌、铟的同步浸出。考察研究了锌中浸渣和锌精矿的投料质量比、初始硫酸浸出剂浓度、浸出时间、液固比、反应温度、浸出时间对锌、铟浸出率行为的影响，研究表明在初始硫酸浓度220g/L，中浸渣与锌精矿质量比1:0.25，粒度-0.074mm，液固比6mL/g，温度90oC，反应时间3h的条件下，锌、铟的浸出率在96%以上，浸出液中95%以上的铁被还原为二价铁离子， 关键词：铁闪锌矿；浸出渣；还原；浸出；锌和铟 中图分类号：TF813 文献标识码：A 文章编号： Reducing Ferric and Leaching of Zinc Indium from Residue Bearing Indium-Zinc-Ferric Zhu Bei-ping1, Deng Zhi-gan2, Zhang Fan2, Wei Chang2, Li Cun-xiong2 (1. Yunnan Hualian Zinc and Indium Co. Ltd. Wenshan 663701, China; 2.Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China) ABSTRACT: ChinaIt?is?rich?of?zinc?resource, most of which exist in forms of marmatitesphalerite of high iron and highbearing indium in China. In order to recycle the valuable metal rich in neutral leaching residues in the process of zinc hydrometallurgy, the testwork of reduction acid leaching on neutral residue mixed with zinc concentrate with high-iron sphalerite as the research object has been taken in the paper. The primary objectives are to leach the zinc and indium remaining in the neutral leach residue as ferrite, using acid, and to reduce the ferric iron in solution to the ferrous state by reaction with zinc concentrate, thereby extracting the zinc and indium in the zinc concentrate.The effecting factors such as mass ratio of neutral residue and zinc concentrate, initial concentration of sulfuric acid, reaction time, liquid-solid ratio, temperature on leaching efficiency of zinc and indium have been studied in detail and finally obtain the best techn