《离子色谱分析钢铁材料中磷的方法研究》-毕业论文（设计）.docVIP

精品论文 Ⅰ 摘 要 测定钢铁及其合金中磷主要有重量法、滴定法、可见光分光光度法、离子色谱法等。这些方法中，离子色谱法因可同时测定几种离子，并且含量在几个数量级变化时都可准确测定，这些优点使离子色谱仪成为极具前景的测磷方法。但是，当今离子色谱仪在检测钢铁方面的研究较少。本实验，以实验室多种钢铁及合金标样为原料，采用1+1硝酸，高氯酸经加热处理的方案溶解金属最优；可选择IC-H柱对钢样除杂，且用原子吸收分光光度计检测发现其使用最佳容量为5mL左右；本用离子色谱仪进中梯度淋洗方案对磷标液及钢样溶液进行检测，发现离子色谱反应灵敏，对钢铁及合金溶液中低浓度的磷检测较为准确。 关键词：离子色谱 钢铁与合金 磷含量 样品前处理 精品论文 Ⅱ ABSTRACT The main determination techniques of Phosphorus in Steel and alloy is Gravimetry, Titration, Visible Light Spectrophotometer Method, Ion Chromatography. About these methods, Ion Chromatography for the simultaneous determination of several kinds of ions contained in samples and content of several orders of magnitude can be measured, it because of these advantages that make the Ion Chromatograph become a promising method of measure Phosphorus. However, nowadays, we have less research for the determination of Phosphorus in steel and alloys. Through the experiment, there are a variety of steel and alloy standard sample as the raw material, I find that use 1+1 nitrate acid and heat them after add some perchloric acid, the scheme of dissolved metals is best, and save time. Then we should choose IC-H to impurity removal, and by using Atomic Absorption Spectrophotometer we can detect that the optimal capacity of IC-H is about 5mL. Then we use gradient elution program to detect Phosphorus standard solution and sample solution. ion chromatographic response is sensitive, Ion Chromatography Instrument is very sensitive and we can use it accurately detect the low concentration Phosphorus. Keywords: Ion Chromatography; Steel and Alloys; Phosphorus; Pretreatment of Sample 精品论文 精品论文 目录 TOC \o 1-3 \h \z \u 摘 要 Ⅰ ABSTRACT Ⅱ 1绪 论 1 1.1 国内外研究现状分析 1 1.1.1 重量法在测定钢铁及其合金中磷的运用 1 1.1.2 滴定法在测定钢铁及其合金中磷的运用 1 1.1.3 光度法在测定钢铁及其合金中磷的运用 2 1.1.4 离子色谱法在测定钢铁及其合金中磷的运用 2 1.1.5 离子色谱法在测定其它物质中磷的运用 2 1.2 总结 3 1.3 离子色谱仪的优点 4 1.4 研究方案 4 2实验部分 6 2.1 实验试剂 6 2.2实验仪器设备 7 2.3 实验原理 7 2.3.1 钢铁及合金溶解原理 7 2.3.2 去除溶解钢样杂质原理 8 2.3.3 离子