《三苯甲烷类化合物的Fenton的降解研究》-毕业论文（设计）.docVIP

lw 三苯甲烷类化合物的Fenton的降解方法研究 摘要：本文探讨了三苯甲烷类化合物的Fenton法降解的效果和影响因素，以孔雀石绿和二甲酚橙为研究对象，研究了H2SO4的量、Fe2+溶液的量、H2O2溶液的量对Fenton反应降解三苯甲烷类化合物的影响效果，并确定各影响因素的最佳量。同时，实验验证了Fenton试剂降解三苯甲烷类化合物的机理是通过产生强氧化性羟基自由基来降解三苯甲烷类化合物。结果表明：Fenton试剂可以快速高效的降解二甲酚橙和孔雀石绿两种化合物，并有非常好的降解效果。当孔雀石绿浓度为60.0mg/L，0.05mol/LH2SO4溶液投加量4.0mL，2g/LFe2+溶液投加量为0.6mL，0.05%H2O2溶液投加量1.0mL，孔雀石绿的降解率达到96%；当二甲酚橙浓度为300.0mg/L，0.5mol/LH2SO4溶液投加量2.5mL，10g/LFe2+溶液投加量为1.2mL，3%H2O2溶液投加量为0.6mL，二甲酚橙的降解率达到97%。 关键词：Fenton法；孔雀石绿；二甲酚橙；降解 Study on?degradation of triphenylmethane compound by Fenton Reagent Abstract: The article study on degradation efficiency of Fenton method on triphenylmethane compound and the factors that affect the degradation process，Malachite Green and Xylenol Orange as the research object in the Fenton reaction，degradation law of Fenton reaction was studied in the initial dosage of H2SO4，Fe2+ solution dosage，H2O2 solution dosage and the best quantity of the influence factors were confirmed．Meanwhile，experimental results showed the mechanism of dyes degraded by Fenton reagents was that it produced strong oxidizing hydroxyl radicals to degradation of triphenylmethane compound．Results showed that Fenton reagents is fast and efficient to degrade Malachite green and xylenol orange and achieved better degradation effects．When the concentration of the Malachite green was 60.0 mg/L，0.05mol/LH2SO4 solution dosing quantity was 4.0mL，2g/LFe2+solution dosing quantity was0.6mL，0.05%H2O2 solution dosing quantity was 1.0mL，the degradation rate reached Malachite green of 96%．When the concentration of the xylenol orange was 300.0mg/L，0.5mol/LH2SO4 solution dosing quantity was 2.5mL，10g/LFe2+ solution dosing quantity was 1.2mL，3%H2O2 solution dosing quantity was 0.6mL，the degradation rate reached xylenol orange of 97%． Key words: Fenton method；Xylenol Orange；Malachite Green；Hydroxyl radicals 1 前言 1.1 三苯甲烷类化合物研究现状 三苯甲烷为斜方叶状晶体，它是三苯甲烷类染料的母体。?三苯甲烷可由 \o 苯 苯在无水三氯化铝存在下与四氯化碳作用，再用 \o 乙醚 乙醚使反应物分解得到一类称为品红的染料，即 \o 三苯甲烷染料 三苯甲烷染料。三苯甲烷类染料是目前痕量分析中一类重要