莫来石的抗氧化涂层.pdfVIP

Available online at Journal of the European Ceramic Society 33 (2013) 191–198 A mullite/SiC oxidation protective coating for carbon/carbon composites Kai-Tong Wang, Li-Yun Cao, Jian-Feng Huang ∗, Jie Fei Key Laboratory of Auxiliary Chemistry and Technologyfor Chemical Industry, Ministry of Education, School of Material Science and Engineering, Shaanxi University of Science and Technology, Xi’an, Shaanxi 710021, PR China Received 5 June 2012; received in revised form 4 August 2012; accepted 6 August 2012 Available online 27 August 2012 Abstract To protect carbon/carbon (C/C) composites against oxidation, a mullite coating was prepared on SiC precoated C/C composites by a hydrothermal electrophoretic deposition process. The phase composition, microstructure and oxidation resistance of the prepared mullite/SiC coatings were investigated. Results show that hydrothermal electrophoretic deposition is an effective route to achieve crack-free mullite coatings. The mullite/SiC coating displays excellent oxidation resistance and can protect C/C composites from oxidation at 1773 K for 322 h with a weight loss rate of only 4.89 × 10−4 g/cm2 h. The failure of the multi-layer coatings is considered to be caused by the volatilization of silicate glass layer, the formation of microholes and microcracks on the coating surface and the formation of penetrative holes between the SiC bonding layer and the C/C matrix at 1773 K. The corresponding high temperature oxidation activation energy of the coated C/C composites at 1573–1773 K is calculated to be 111.11kJ/mol. © 2012 Elsevier Ltd. All rights reserved. Keywords: Carbon/carbon composites; Mullite coating; Hydrothermal electrophor