《年产50000吨十二烷基苯磺酸的工艺设计》-毕业设计(论文).docVIP

林海：年产50000吨十二烷基苯磺酸的模拟设计 PAGE II 年产50000吨十二烷基苯磺酸的工艺设计 摘 要 本文阐述了表面活性剂发展的历史和发展现状，以及在未来的发展趋势；介绍了表面活性剂十二烷基苯磺酸的性质、用途、原料选择以及常见的合成方法。描述了三氧化硫磺化法的技术进展、磺化器的分布情况和磺化新技术的开发利用。重点对以硫磺为原料在过量干空气中直接燃烧生成二氧化硫，二氧化硫再经钒催化氧化转化生成三氧化硫，三氧化硫磺化烷基苯法制备十二烷基苯磺酸纳做了详尽的工艺设计。对整个生产过程中的物料和能量进行了衡算，对磺化器参数进行计算，用AutoCAD将磺化工艺流程图、磺化器设备图和厂房布置图进行了绘制，并在最后展望了三氧化硫磺化法的发展前景。 关键词：烷基苯磺酸；三氧化硫；磺化工艺；物料衡算和能量衡算 Annual produces 50,000 tons dodecylbenzenesulfonic acid process design Linhai (Biochemistry college ， Anhui University of Technology and Science，Chemical Engineering and Technology 071 3070404128 ) Abstract Chapter one of this text has comparatively explained history of surface-active agent development and current situation of the development exhaustivly, and the future trend of development; Introduced the surfactant dodecylbenzenesulfonic acid the properties, applications and material selection and common synthesis method. Describes the method of preparing sulphonated sulphur trioxide technology progress, the distribution of sulphonated device and preparing sulphonated the development of new technology use; Chapter two introduced the sulfonic acid common synthetic method of 12 alkyl benzene of surface-active agent. Oxidize on three sulphur sulphonating alkyl benzene legal system prepare against 12 alkyl benzene sulfonic acid make exhaustive technological design especially. the entire production process of materials and energy balance, of sulfonation calculated parameters, sulfonation process will use AutoCAD Map, sulfonation plant equipment layout plan and a rendering,and looking at the final sulfur trioxide sulfonation of the prospects for the development of law. Keywords: alkyl benzene sulfonic acid; Sulphur trioxide; Preparing sulphonated craft; Material calculation and energy calculation 目录 TOC \o 1-3 \h \u 25579 引言 - 1 - 20502 第1章 概述 - 2 - 29587 1.1磺酸的简介 - 2 - 6673 1.2磺酸的生产方法及特点 - 2 - 22753 1.3磺化工艺的简介 - 3 - 5638 1.4磺酸的磺化技术的发展与现状 - 4 - 139 1.5课题研究的意义、内容和目的 - 5 - 28431 第2章 反应原理 - 6 -