制钒废水中铬的回收工艺研究-毕业设计(论文).docVIP

PAGE XXVIII 四川理工学院毕业设计（论文） 制钒废水中铬的回收工艺研究 学 生： 专 业：化学工程与工艺 指导教师： 四川理工学院材料与化学工程学院 四川理工学院毕业论文（设计） 中文摘要 I 制钒废水中铬的回收工艺研究 摘 要 鉴于现在钒工业废水中，钒、铬等重金属对生物体和生态环境的破坏，以及重金属的经济价值和工业应用价值，本论文研究了强碱性苯乙烯系阴离子交换树脂（717#树脂）对水溶液中钒、铬的吸附情况。采用了单因素实验和正交实验从不同温度、pH值、流速等条件研究了717#树脂对铬的吸附率。探讨了717#树脂的吸附静态学和吸附柱动力学。研究发现，717#树脂对废水中的V(V)、Cr(VI)的平衡吸附量分别为 7.8g/L、27.3g/L，显示了较高的离子选择性,其吸附效果较好。717#树脂对V(V)、Cr(VI)的吸附，其中pH值对其吸附平衡的影响较大，流速对其吸附平衡的影响其次，温度对吸附平衡的影响不是很明显，但也不可忽略；钒、铬废水经717#树脂吸附后，铬的回收率可高达99%以上，废液中铬的含量基本能达到国家排放标准。 关键词：废水，吸附，铬的回收 四川理工学院毕业论文（设计） 英文摘要 II Study on Technologic conditions of Recovering Chromium from Waste Water of Manufacturing Vanadium ABSTRACT The V (V)、 Cr (VI) and other heavy metals in vanadium-containing wastewater damage the organisms and ecological environment ,as well as the economic value and the applications value in industrial. So the adsorption of vanadium and chromium ion about the exchange resin of alkaline styrene series (717# resin )was discussed in this article. The adsorption of V (V), Cr (VI) on 717# resin was studied under the different temperatures, pH value and velocity conditions. And adsorption statics, column adsorption kinetics of 717# resin was disscussed. The study find that 717# resin’s adsorption equilibrium of V (V), Cr (VI) was 7.8g / L, 27.3g / L in wastewater , which show a high ion-selective and the better adsorption effect . pH value was the greater impact to adsorption equilibrium, velocity was the second to adsorption equilibrium, and the temperature to the adsorption equilibrium is not clear but can not be ignored regarding the adsorption of V (V), Cr (VI) on 717# resin.