共轭聚合物光伏材料.pptVIP

以 thienylene-vinyl 为共轭支链的聚噻吩乙烯 溶液吸收光谱 膜吸收光谱 电化学循环伏安图 不同电位下的吸收光谱 电位值相对于Ag/Ag+ Photovoltaic properties of the polymer solar cells based on the blend of polymer/PCBM (1:1, w/w) under the illumination of AM 1.5, 100 mW/cm2. Polymers Voc (V) Isc (mA/cm2) FF PCE (%) BiTV-PTV3 0.48 2.27 0.30 0.32 P3HTV1 0.51 1.24 0.31 0.21 P3HTV2 0.51 1.30 0.32 0.26 1The device in this work with the weight ratio of P3HTV: PCBM = 1:1. 2 The device in our previous work22, where the weight ratio of P3HTV to PCBM was 1:2. ［Jianhui Hou, et al., Macromolecules, 2006, 39，4657-4662.］ 外量子效率对比 以 terthiophene-vinyl 为共轭支链的聚噻吩 溶液吸收光谱 膜吸收光谱 空穴迁移率（ cm2/Vs ）： 2D-PT-TThV10： 1.16×10-4 2D-PT-TThV20： 6.35×10-4 2D-PT-TThV30： 3.48×10-4 2D-PT-TThV40： 4.27×10-5 光伏特性 ? Polymers Voc (V) Isc(mA/cm2) FF(%) PCE(%) 2D-PT-TThV0 0.68 3.80 34 0.87 2D-PT-TThV10 0.58 6.58 39 1.47 2D-PT-TThV20 0.73 6.85 38 1.91 2D-PT-TThV30 0.74 5.69 39 1.65 2D-PT-TThV40 0.63 6.42 36 1.47 ［Erjun Zhou, et al., J. Phys. Chem. B, 2006, 110, 26062-26067] PTZV-PT Hole mobility: SCLC method: 4.7 × 10-3 cm2 V-1s-1 FET mobility: 6.8 × 10-3 cm2V-1s-1 [Yingping Zou, Weiping Wu, et al., Macromolecules, 2007, 40: 7231-7237 ] Cross linked polythiophenes with conjugated bridges Y.F. Li, Y.P. Zou, Adv. Mater., 2008, 20, 2952-2958. 共轭桥连的交联型聚噻吩衍生物 P1 0.54 2.22 25 0.37 P2 0.66 3.79 34 1.05 P3 0.72 4.06 35 1.26 Polymers Voc (V) Isc(mA/cm2) FF(%) PCE(%) P4 0.75 2.61 32 0.78 Table Photovoltaic performance of the polymer solar cells based on P1-4 under AM 1.5, 80 mW/cm2 . [Erjun Zhou et al., Macromol. Rapid Commun. 2006, 27: 793–798. ] 用空间电荷限制电流方法测量的空穴迁移率为 P1： 5.23×10-6 cm2/Vs P2：1.28×10-4 cm2/Vs P3：7.0