汽车用高品质非调质钢中非金属夹杂物研究 .docVIP

汽车用高品质非调质钢中非金属夹杂物研究 汽车用高品质非调质钢中非金属夹杂物研究 卓晓军1 杨成威1 王万军1 王新华1崔京玉2 常开地2 王 坤2 (1.冶金与生态工程学院,北京科技大学,北京100083;2.首钢技术研究院,首钢集团,北京100041 摘要对采用“顶底复吹转炉炼钢-LF精炼-VD真空处理-喂硫线增硫”工艺路线,生产汽车用非调质钢铸坯的全过程,特别是对非金属夹杂物进行了系统的研究。试验证明采用本研究制定工艺路线,非调质钢[P]含量控制在0.012%以下,T[O]含量控制到0.001%左右。LF精炼过程钢水[N]含量呈略微增加。而钢水T[O]含量降低较快,T[O]由0.04%降低至0.002%。钢中夹杂物以纯MnS夹杂物为主,有少量的氧化物?MnS复合夹杂物。 经过VD真空处理,钢水T[O]含量由LF精炼结束时的0.002%降低至0.0011%,[N]则由LF结束时的0.008%降低至0.0048%。氩气软吹后,钢液的T[O]增加了0.0002%。经真空处理后以及喂线后,钢水试样中除硫化物之外,已很难发现氧化物类夹杂。浇铸过程中间包钢水试样中非金属夹杂物,绝大多数夹杂物为钢水凝固末期生成的硫化物和氮化物,很难观察到氧化物类夹杂物。连铸坯中观察到的非金属夹杂物绝大部分是纯MnS夹杂物,尺寸较大呈浅色不规则形状。铸坯中能观察到一些氧化物夹杂,这些氧化物和MnS组成复合的夹杂物,呈深色在MnS夹杂物的中心,其尺寸较小约为2μm,此类夹杂物是由于保护浇铸不善而产生的。此外还能观察到尺寸较小的TiN-VN类夹杂物,为凝固末端生成。 关键词非调制钢超低氧LF精炼VD真空处理非金属夹杂物 Study on Non-metallic Inclusions of High Quality Microalloyed Forging Steel for Automobile Zhuo Xiaojun1Yang Chengwei1Wang Wanjun1Wang Xinhua1 Cui Jingyu2Chang Kaidi2Wang Kun2 (1.School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing, 100083; 2.Technical Research Institute,Shougang Group,Beijing, 100041 Abstract The manufacture process and non-metallic inclusions of microalloyed forging steel for Automobile was investigated systematically. Phosphorus content and total content could be control below 0.012%and around 0.001% respectively with this technics. During ladle furnace (LF refining process, nitrogen content increased a little bit, while total oxygen content decreased rapidly from 0.04%to 0.002%. MnS inclusions were dominant with few oxide inclusions in steel. During vacuum degasser (VD treatment, total oxygen content deceased from 0.002%to 0.0011%, while nitrogen content decreased from 0.008%to 0.0048%too. After soft blowing, total oxygen content increased 0.0002%. After VD vacuum treatment, no oxide inclusion could find except MnS inclusion. During the casting, there was no oxide to be found. Only MnS and carbide inclusions were found which were expected to be formed at the end of solidification. Most inclusions were