Ti-Al系金属间化合物多孔材料的制备和性能.docVIP

214Vol.21No.4 20078CHINESE JOURNAL OF MATERIALS RESEARCH August 2007 Ti–Al ? 11112 1. 410083 2. 210009 , Ti–Al , . :Ti–Al ; , ( 60%, ; Kirkendall . , Ti–Al , , Kirkendall , TG1461005-3093(200704-0337-06 Preparation and characteristics of Ti–Al based alloy porous material HUANG Hujun 1HE Yuehui 1?? JIANG Yao 1HUANG Baiyun 1XU Nanping 2 1.State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083 2.Membrane Science and Technology Research Center, Nanjing University of Technology, Nanjing 210009 *Supported by National Natural Science Foundation of China No Manuscript received July 28, 2006, in revised form November 30, 2006. **To whom correspondence should be addressed, Tel:(07318836144,E–mail:yuehui@mail.csu.edu.cn. ABSTRACT Ti–Al based alloy porous materials were fabricated through cold pressing and pressureless sintering of Ti/Alelemental powder mixtures. The in?uence of Al content on the swelling behavior, pore structure properties and pore formation mechanism were investigated in detail. The results show that swelling e?ect and pore formation take place because of the di?erent di?usivities of Ti and Al during reaction sintering. The swelling and porosity increase with increasing of the Al content, but when the Al content(massfractionexceeds 60%,the swelling begins to suppress and the porosity begins to decrease. The prime reason for the pore formation is considered to be the existence of the porosity in green compacts and Kirkendall e?ect in the process of reactive synthesis. KEY WORDS metallic materials, Ti–Al alloy, porous material, Kirkendall e?ect, swelling behavior [1, 2], . , [3～ 8]. , , , , , [2, 9]. Ti–Al , Ti Al 2006728; :, [10], Ti–Al [11], [12] /[13], Ti Al Kirkendall [14]. , Ti–Al . Ti–Al [15], [16]. Ti Al Ti–Al , 33821 1(, % Table 1Composition of the samples with di?erent Al content (massfraction, % Sample No. 12345678910 Al content 20253035404550556065 Ti content 80757065605550454035 . 1 99.7%T