Raney-Cu论文纳米多孔催化剂和光催化剂的制备及其性能研究.docVIP

Raney-Cu论文：纳米多孔催化剂和光催化剂的制备及其性能研究 【中文摘要】由于“协同效应”或“双功能机理”现象的存在,复合金属催化剂往往较单一金属催化剂具有更好的催化性能,如高选择性、高活性、高稳定性等。纳米多孔金属材料尤其是纳米多孔复合金属材料作为一种具有功能及结构双重属性的新颖材料,其制备及应用研究开始引起人们的极大关注。本论文主要研究了纳米多孔金属催化材料(包括Raney-Cu、Au/Raney-Cu、Au@Raney-Cu、Pt/NPG、Pd/NPG、Cu/NPG等)的制备、表征及其对醇类(苯甲醇和葡萄糖)的选择性催化氧化性能；以及Bi-Ti-O系光催化剂的脱合金法制备及其光催化性能。具体内容包括：一、制备了系列Raney-Cu基多孔催化材料：1、通过简单的原位 【英文摘要】Due to the existence of synergistic effect and bifunctional mechanism, the composite metal catalysts usually exhibit a better catalytic performance than the single-metal catalysts, such as the selectivity, activity and stability for the reactions. In the past several years, the porous metallic materials have been developed rapidly, especially the materials with several kinds of metals, as they are a category of novel engineering materials with the dual properties both in function and structure.In this thesis, the researches mainly focus on the preparation, characterization and catalytic oxidation of alcohols (mainly benzyl alcohol and D-glucose) of the nano-porous catalysts (including Raney-Cu, Au/Raney-Cu, Au@Raney-Cu, Pt/NPG, Pd/NPG, Cu/NPG, and so on). Besides, there is also the preparation of Bi-Ti-O based photocatalyst and its photocatalytic properties.The main information is as follows:First of all, the preparation of a series of Raney-Cu-based catalysts.First, we prepared two kinds of Raney-Cu based samples (Au/Raney-Cu and Au@Raney-Cu) through a spontaneous irreversible redox procedure. The structural and chemical properties of the samples were characterized using X-ray diffraction (XRD),scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS).The catalytic activities of the catalysts were tested by gas-phase selective oxidation of benzyl alcohol to benzaldehyde using oxygen as the oxidants.From the results, it was found that in the sample Au/Raney-Cu, gold was in the form of Au0, while in the sample Au@Raney-Cu, gold was in the form of Auα+. If Au was in the form of the above cases, the catalyti