不对称羟胺化反应.pptxVIP

光活性的α-羟基醛酮结构单元存在于很多重要的天然产物中，而且是很重要的合成子。醛酮的α-羟胺化反应是构建光活性的α-羟基醛酮结构单元的一个很新颖的方法。; Hisashi Yamamoto was born in Kobe, Japan, in 1963. He received his Bachelor’s degree from Kyoto University in 1967, where he got his start in a research group headed by Prof. H. Nozaki. Professor Yamamoto received his Ph.D. from Harvard University under mentorship of Corey. Yamamoto has become aware of the importance of chiral Lewis acids in asymmetric synthesis. In 1985, he first introduced binaphthol as a ligand for chiral Lewis acid catalysts. This work was the forerunner of a vast amount of presen