应用电化学第一章电化学基础.pptVIP

1.4.2 Butler-Volmer equation when E=Ee, no net current flows, there is a dynamic equilibrium at the electrode surface electrode reaction By convention, anodic currents are taken as positive. Io is known as the exchange current density. The experimental current (or net current, or polarized current) 提示：see p9 fig.1.3 The relationship between I and E? Butler –Volmer equation (basic equation of electrochemical polarization) The equilibrium potential Ee and the exchange current density Io together totally characterize the equilibrium situation at an electrode. 如何理解？