有机锆试剂在有机合成中的使用.pdfVIP

Organozirconium reagents in organic synthesis 23 M2 Yasuhiro Kondo / /07 2011 Cl 2 2 ; [Kr] 5s 4d , EN; 1.33 Cp ZrCl = Zr 2 2 Cl IIIVZr Zr(IV), 16e, d0 Natural products synthesized via Zr-promoted reaction HO OH H H H O H H N H OH N OH Me (-)-macronecine (-)-dendrobine 7-epi--bulnesene O OH OH phorbol O HO C O O 2 H O HO C O 2 Bu CO H 9 O 2 OH O O Coenzyme Q10 reveromycin B CO H 2 HO H