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that和which虽然都能指物，但是在某些情况下，只能用that指物而不用which
1）先行词被形容词最高级修饰时，例如：
This is the most interesting movie that I have ever seen.（作宾语可省略）
This is the most beautiful park that we have visited.
2）先行词被the very，the only the same, the last等修饰时，例如：
This is the very book that Im looking for.（作宾语，可省略）
The only thing that she could do was to wait patiently.（作宾语，可省略）
3）先行词被序数词修饰时，例如：
The first thing that we do in the morning is to clean the classroom.（作宾语，可省略）
This is the third largest city that was founded in the 1980s.（作主语）
4）当先行词是anything, everything, nothing (something 除外), few, all, none, little, some
等代词时，或者是由every, any, all, some, no, little, few, much，each等修饰时
Have you taken down everything (that) Mr. Li has said?
There seems to be nothing (that) seems impossible for him in the world.
All that can be done has been done.
There is little (that) I can do for you.
5）当先行词前面有who, which等疑问代词时
Who is the man that is standing there?
Which is the T-shirt that fits me most?
6)、当先行词既有人，也有动物或者物体时
Can you remember the scientist and his theory that we have learned?
7）先行词是主句的表语或关系代词在从句中作表语，例如：
He is not the boy that he used to be.
China is no longer the country that it used to be.
8).当在there be句型中，通常情况下用that，不用which
宜用which而不用that的情况
1. 在非限制性定语从句中。
Bamboo is hollow, which makes it light.
2. 在关系词前有介词时。
This is the room in which Chairman Mao once lived.
3. 当先行词本身是that时。
The clock is that which can tell us the time
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