类质同象铁离子对铁闪锌矿晶体结构及可浮性的影响.pdfVIP

类质同象铁离子对铁闪锌矿晶体结构及可浮性的影响 Effect of iron concentration on the crystallization, electronic strcuture, and floatability of sphalerite 邓久帅 赖浩 Jiushuai Deng Hao Lai A u g u s t 2 3 , 2 0 1 8 Outline 1 Background 2 Theoretical calculations 3 Effect of iron concentrion on the copper activation of sphalerite 4 Effect of iron concentrion on the xanthate adsorption of sphalerite 5 Conclution 6 Acknowledgments 1 Background Marmatite is one of the most important zinc sulfide minerals and is widely distributed throughout the world, which is generally formed by substituting Fe for Zn in sphalerite crystals. The Fe impurity of sphalerite has an important effect on its crystallization, elect ronic st rcut ure, and f loatability. I n addit ion, copper act ivat ion and xant hate adsorption are the key to flotation of sphalerite. p Previous studies mainly focus on the processing procedure used for flotation or the development of new activating agents. In terms of theoretical studies, the results for the effects of Fe on sphalerite crystal properties and copper activation mechanism are conflicting. p I n pre se nt w o r k, t he ef f e ct s of i ro n c o nc e nt rat io n o n t he crystallization, electronic strcuture, copper activation and xanthate adsorption of sphalerite were systematically studied by theoretical calculations and experiments. Harmer, S. L., et al. Minerals Eng ineering, 2008. Ye, Chen, et al. Minerals Eng ineering, 2012. 2 Theoretical calculations 2.1 Influence of Fe concentration on the geometric structure of sphalerite