酚醛树脂的改性研究与进展.pdfVIP

酚醛树脂的改性研究与进展 摘要 摘 要 酚醛树脂是首个应用于工业化生产的塑料，它具有较高的机械强度、良好的 绝缘性、高残碳率、低烟低毒、耐热、耐腐蚀、抗化学性等特性。 本文主要综述世界各地的学者专家关于酚醛树脂进行改性的近几年的研究成 果，通过对酚醛树脂改性来提高其耐热性和增强韧性，使其制品更加满足日益增 长的市场需求。如通过利用橡胶、聚砜、梓油和合成树脂等改性酚醛树脂增强韧 性；通过硼、有机硅、无机钠米粒子和纤维、聚酰亚胺树脂等改性酚醛树脂提高 酚醛树脂的耐热性。 关键词：酚醛树脂；耐热性；韧性；改性 I Abstract Abstract Phenolic resin is plastic first into a variety of industrial production, it has high mechanical strength, good insulation, high carbon residue rate, low smoke, low toxicity, heat resistance, corrosion resistance, chemical resistance and other characteristics. This paper mainly summarizes the domestic and foreign experts and scholars of phenolic resin were modified in recent years of research results, through the modified phenolic resin to improve its heat resistance and toughness enhancement, to make the products more to meet the growing market demand. For example through the use of rubber, polysulfone, stillingia oil, synthetic resin, and so strengthen toughness of modified phenolic resin; by boron, silicon, inorganic nano particles and fibers, polyimide resin modified phenol formaldehyde resin to improve the heat resistance of phenolic resin. Keywords: Phenolic resin ，Heat resistance ，Modification ，Toughening II 目录 目 录 1 引言1 2 酚醛树脂的改性研究1 2.1 酚醛树脂的增韧改性1 2.1.1 橡胶复合改性酚醛树脂 1 2.1.2 聚砜改性酚醛树脂2 2.1.3 梓油改性酚醛树脂3 2.1.4 合成树脂改性酚醛树脂 4 2.2 酚醛树脂的耐热改性6 2.2.1 硼改性酚醛树脂 6 2.2.2 有机硅改性酚醛树脂7 2.2.3 无机纳米粒子和纤维改性酚醛树脂9 2.2.4 聚酰亚胺树脂