陈东uv技术在薄膜涂料中的应用湛新树脂.doc

Innovative Energy Curing Technology for Film Coatings UV技术在薄膜涂料中的应用 RADTECH CHINA 2014 Adon Chen Contents 内容提要 ? New tin-free high functionality 100 % UV hardcoat oligomers with improved properties: EBECRYLTM 8602 and EBECRYL 8415 不含锡的加强型高官能100%UV高硬度涂料树脂: EBECRYL 8602 和 EBECRYL 8415 ? UV Resin for Energy Curable anti-fog Coatings: KRM 8713B 用 于能量固化防雾涂层的UV树脂: KRM 8713B ? A Novel Specialty WB UV Resin UCECOATTM 7210 as WB UV flexibilizer for UCECOAT 7200 UCECOAT 7200的水性UV柔韧 性树脂搭档: 新型特种水性UV树脂UCECAOT 7210 New tin-free high functionality 100 % UV hardcoat oligomers with improved properties: EBECRYL 8602 and EBECRYL 8415 不含锡的加强型高官能100%UV高硬度 涂料树脂: EBECRYL 8602 和 EBECRYL 8415 Scope 展望 New challenges have appeared for coating formulators 涂料配方 面临新的挑战: o Growing preference for tin-free resins 对不含锡树脂的需求 日益增长 o Achieving higher performances (scratch and abrasion resistances) 更高的性能要求 （耐刮耐磨性能） o Applying at lower coatweight and/or lower curing energy … but still achieving high hardcoat performance 低膜厚应用和 低能量固化条件下仍然要求达到高硬度的性能表现 ? Allnex has developed two new energy curable resins to answer these challenges 为此湛新专门开发了两款能量固化树脂: 9 functional EBECRYL 8602 10 functional EBECRYL 8415 Form of delivery 样品形态 ? EBECRYL 8602: o Tin-free 不含锡 o Undiluted 9 functional aliphatic urethane acrylate 未稀释的9官能脂肪族聚氨酯丙烯酸酯 o Color = 100 APHA max. 色值 = 最大100 APHA o Approx. 3000 mPa.s (60°C) 粘度大约3000 mPa.s ? EBECRYL 8415 o Tin-free 不含锡 o Undiluted 10 functional aliphatic urethane acrylate 未稀释的10官能脂肪族聚氨酯丙烯酸酯 o Color = 100 APHA max. 色值 = 最大100 APHA o Approx. 1700 mPa.s (60°C) 粘度大约1700 mPa.s Pencil hardness 铅笔硬度 5H 4H 3H 2H H F EBECRYL 8602 EBECRYL 8415 EBECRYL 1290 DPHA Formulation : oligomer / MEK / ADDITOLTM CPK/ = 100 / 100 / 3 配方 : 树脂/丁酮/ADDITOL CPK/=100/100/3 Substrate 材质: Glass 玻璃 Coating : 10μm thickness, bar coating on each substrates 涂层 : 10μm膜厚, 刮棒刮涂在各材质上 Drying : 60?C X 5 minutes 干燥 : 60?C X 5分钟 UV curing : 120W/cm, 5 m/min, two pass UV固化: 120瓦/厘米贡灯, 5米/分钟, 固化两遍 Evaluation : Mitsubishi Uni, 500g wei