结构化学 分子对称性教学内容.pptVIP

群的定义 1、封闭性： 2、主操作： 3、逆操作： 4、结合律： 群的实例 群的乘法表 规则：先行后列，（列行） 分子点群的分类 Cn，Cnh， Cnv， Cni， Sn， Dn， Dnh， Dnd, T, Th, Td, O, Oh, I, Ih Point groups Point groups are a way of classifying molecules in terms of their internal symmetry. Molecules can have many symmetry operations that result into indistinguishable configurations. Different collections of symmetry operations are organized into groups. These 11 groups were developed by Schoenflies. C1: only identity. Example: CHBrClF Cs: only a reflection plane. Example: CH2BrCl Ci: only a center of symmetry. Example: staggered 1,2-dibromo-1,2-dic