无机化学课件06 group IIIA.pptxVIP

Group IIIA, (Group 13);GROUP 3A; The lower oxidation states become more important down the group -- ionic Tl exist primarily in the +1 oxidation state Related to the inert pair effect – the fact that the heavier elements lose their np electrons but not their ns electrons Lower oxidation state oxides are more basic;BORON;Sources ;Structures of Elements;二十面体; Halides;Boron halides are highly reactive, volatile compounds. The gas BF3 acts as a Lewis acid with ammonia. ;General Properties;Boron Subhalides;Metal Borides;Hydrides;Bonding in Diborane;3c2e Bonds in Diborane;3c2e Bonds;Electron