晶体缺陷作业.pdfVIP

. 1 什么叫肖特基缺陷和弗兰克耳缺陷？用 Kroger-Vink 记号分别描述 AgBr 中的 弗兰克耳缺陷和 MgO中的肖特基缺陷形成的缺陷化学方程，写出 ZnO 中掺杂 Al 2 O3 空位补偿和电子补偿的缺陷化学方程。 2 If cupric oxide (CuO) is exposed to reducing atmospheres at elevated temperatures, 2+ + some of the Cu ions will become Cu . (a) Under these conditions, name one crystalline defect that you would expect to form in order to maintain charge neutrality. + (b) How many Cu ions are required for the creation of each defect? (c) How would you express the chemical formula for this nonstoichiometric material? + 2+ 3 (a) Suppose that Li O is added as an impurity to CaO. If the Li substitutes for Ca , 2 what kind of vacancies would you expect to form? How many of these vacancies are created for every Li added? - 2- (b) Suppose that CaCl is added as an impurity to CaO. If the Cl substitutes for O , 2 what kind of vacancies would you expect to form? How many of the vacancies are - created for every Cl added? 4 纯铁的空位形成能为 1.5X10-19 J/atom ，将纯铁加热至 850℃后激冷至室温 20℃, 若高温下的空位全部保留，试求过饱和空位浓度与室温平衡空位浓度的比值。 5 已知铜的晶体结构为 fcc, 点阵常数 a=0.225nm，切变模量 10 2 G 4 10 N m ，试 分别计算柏氏矢量为 a [10 1] a [11