非金属原子簇的化学.pptVIP

The Discovery Of FullerenesWinning The 1996 Nobel Prize For Chemistry C60-Fullerene at 153 deg.K. C60 crystallizes in a face centered cubic arrangement. This refinement is in space group Pa3. H.-B.Burgi,E.Blanc,D.Schwarzenbach,Shengzhong Liu,Ying-jie Lu,M.M.Kappes, J.A.Ibers, Angew.Chem.,Int.Ed.Engl., 31, p640,1992 2、金属富勒烯的类型 （1） 外掺型化合物 RbCs2C60 （2）包合物 La@C60 Sc2@C84 （3）外接衍生物 C60Pt(Pph3)2 （4）取代物 C59N Polymeric fullerene chains in RbC60 Peter W. Stephens, G. Bortel, G. Faigel,M Tegze, A. Janossy, S. Pekker, B. Oszlanyi, and L.Forro, Nature, 370, 1994 p 636-6