基于苝酐和三联吡啶有机凝胶因子的设计及性质研究.pdfVIP

摘 要 摘 要 近年来，新型自组装有机小分子凝胶作为一种软材料引起了人们广泛的关注。 利用有机合成的方法，本文主要研究了两种小分子凝胶，一类是基于3,4,9,10-苝四羧 酸二酐的荧光增强小分子有机凝胶；另一类是基于三联吡啶羧酸的对有机酸和无机 酸具有识别作用的小分子水凝胶。并对这两种小分子凝胶的成胶性能、微观形貌、 潜在应用等等进行了详细研究，具体的研究内容如下： 1) 制备并表征了基于苝二酰亚胺 （PBI）发色团的分子系统PBI1和PBI2。通过 酸和咪唑单元之间的其他非共价氢键相互作用，稳定的胶凝剂PBI2可自组装成纠缠 的超分子纤维，从而形成由DMSO 中的超声触发的荧光增强凝胶。此外，还对结构 变化和凝胶方法对凝胶性能的影响进行了对比和研究。 2) 设计并合成了两种包含顺、反环己二胺和三联吡啶羧酸的凝胶因子TD,该凝 胶因子可以对Sn4+进行选择性响应，并且可以对有机酸中的酒石酸和无机酸中的磷 酸、盐酸进行鉴别。并通过电子显微镜、XRD、荧光紫外光谱仪等化学仪器对凝胶 的微观结构、堆积方式的变化及光谱性质等等进行了详细研究。 综上所述，我们设计合成了基于苝酐和三联吡啶的有机凝胶因子，并对这两种 小分子凝胶进行了性质研究。实验研究发现，这些凝胶可以在超声诱导下荧光增强， 并能对无机酸和有机酸进行选择性可视化识别。 关键词 苝二酰亚胺；三联吡啶羧酸；小分子凝胶；超声诱导；荧光调控 I Abstract Abstract In recent years, new self-assembled organic small molecule gels have attracted widespread attention as a soft material. Using organic synthesis methods, this paper mainly studies two kinds of small molecule gels. One is based on 3,4,9,10-Perylenetetracarboxylic dianhydride, and the other is based on Terpyridine carboxylic acid that recognizes organic and inorganic acids. The gelation properties, micro-morphology, potential applications, etc. of these two small-molecule gels were studiedindetail.Thespecificresearchcontentsareasfollows: 1) The molecular systems PBI1 and PBI2 based on Perylene Bisimide (PBI) chromophore were prepared and characterized. Through other non-covalent hydrogen bondinginteractionsbetweentheacidandtheimidazoleunit,thestablegellingagentPBI2 can self-assemble into entangled supramolecular fibers, thereby forming a fluorescence-enhanced gel triggered by ultrasound in DMSO. In addition, the effects of structuralchangesandgelmethodsongelpropertieswerecomparedandstudied. 2) Twogel factorsTD containing cis andtrans cyclohexanediamine andterpyridine carboxylic acidwere desig