二硼化锆基超高温陶瓷的制备及性能_英文_.docxVIP

· 1590 · 硅 酸 盐 学 报 2007 年 第 35 卷第 12 期 硅 酸 盐 学 报 Vol. 35，No. 12 2 0 0 7 年 1 2 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY December，2007 二硼化锆基超高温陶瓷的制备及性能 王海龙 1,2，汪长安 2，张 锐 1，黄 勇 2，方岱宁 3 (1. 郑州大学材料科学与工程学院，郑州 450000；2. 清华大学，新型陶瓷与精细工艺国家重点 实验室，北京 100084；3. 清华大学航空航天学院，北京 100084) 摘 要：用碳化硅(SiC)颗粒增韧二硼化锆(ZrB2)陶瓷，在氩气流中热压烧结温度为 1 950 ℃、保温 1 h，20 MPa 压力下成功制备出了致密的 ZrB2/SiCp 复合材料。ZrB2/SiCp 复合材料的致密度随着 SiC 颗粒添加量的增加而增加。当 SiC 颗粒的体积分数(下同)为 15%时，相对致密度达到 100%。ZrB2/SiCp复合材料的抗弯强度和断裂韧性都随着SiC 添加量的增加成上升趋势，当SiC 颗粒的添加量在15%时同时达得最大值，分别为646 MPa 和8.52 MPa·m1/2。 SiCp 的添加还提高了 ZrB2/SiCp 复合材料的耐氧化烧蚀性能。 关键词：超高温陶瓷；二硼化锆；热压烧结；性能 中图分类号：TB333 文献标识码：A 文章编号：0454–5648(2007)12–1590–05 PREPARATION AND PROPERTIES OF ZIRCONIUM DIBORIDE-BASED ULTRA-HIGH TEMPERATURE CERAMICS WANG Hailong1,2，WANG Changan2，ZHANG Rui1，HUANG Yong2，FANG Daining3 (1. School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450000; 2. State Key Laboratory of New Ceramics and Fine Processing, Tsinghua University, Beijing 100084; 3. School of Aerospace, Tsinghua University, Beijing 100084, China) Abstract: Zirconium diboride (ZrB2)-based ultra-high temperature ceramics (UHTC) reinforced by silicon carbide (SiC) particles were prepared by hot press sintering at 1 950 ℃ for 1 h under 20 MPa pressure in an argon flow. The relative density of ZrB2/SiCp composites increased with the content of SiC addition, and reached 100% when 15% (in volume) SiC particles were added. The bending strength and toughness of the composites also increased with increasing SiC amount, and reached values of 646 MPa and 8.52 MPa·m1/2, respectively, at 15% SiC addition. Furthermore, the addition of SiC particles improved the resistance to oxida-tion/ablation of ZrB2/SiCp composites. Key words: ultra-high temperature ceramics; zirconium diborde; hot press sintering; property Ultra-high temperature ceramics (UHTCs) are usua-lly defined as ceramic materials that can be used at tem-peratures in excess of 2 000 ℃.[1] The characteristics of UHTCs, such as their