中国科学院大学-高等有机化学-第八章-涉及过渡金属的反应-Chapter 8 Reactions Involving Transition Metals.ppt

下载文档

2
0
约8.57千字
约 138页
2021-01-13 发布于湖北
举报
版权申诉
保障服务

中国科学院大学-高等有机化学-第八章-涉及过渡金属的反应-Chapter 8 Reactions Involving Transition Metals.ppt

1、本文档共138页，可阅读全部内容。
2、原创力文档（book118）网站文档一经付费（服务费），不意味着购买了该文档的版权，仅供个人/单位学习、研究之用，不得用于商业用途，未经授权，严禁复制、发行、汇编、翻译或者网络传播等，侵权必究。
3、本站所有内容均由合作方或网友上传，本站不对文档的完整性、权威性及其观点立场正确性做任何保证或承诺！文档内容仅供研究参考，付费前请自行鉴别。如您付费，意味着您自己接受本站规则且自行承担风险，本站不退款、不进行额外附加服务；查看《如何避免下载的几个坑》。如果您已付费下载过本站文档，您可以点击这里二次下载。
4、如文档侵犯商业秘密、侵犯著作权、侵犯人身权等，请点击“版权申诉”（推荐），也可以打举报电话：400-050-0827(电话支持时间：9:00-18:30)。

9.2. Organosilicon Compounds 9.2.1. Synthesis of Organosilanes 2 1 9.2. Organosilicon Compounds 9.2.1. Synthesis of Organosilanes 2 1 9.2.2. General Features of Carbon-Carbon Bond-Forming Reactions of Organosilicon Compounds Silicon provides stabilization for carbon cation at the beta position. This stabilization is attributed primarily to hyperconjugation with the C–Si bond 9.2.2. General Features of Carbon-Carbon Bond-Forming Reactions of Organosilicon Compounds 9.2.3. Additions Reactions with Aldehydes and Ketones 9.2.3. Additions Reactions with Aldehydes and Ketones (CH3)3Si(NO3SCF3) is generated in situ from triflimide 9.2.3. Additions Reactions with Aldehydes and Ketones 2 1 9.2.3. Additions Reactions with Aldehydes and Ketones 2 1 9.2.3. Additions Reactions with Aldehydes and Ketones 2 1 9.2.3. Additions Reactions with Aldehydes and Ketones 2 1 9.2.3. Additions Reactions with Aldehydes and Ketones 2 1 nucleophilic reactivity of allylic silanes can be enhanced by formation of anionic adducts 9.2.3. Additions Reactions with Aldehydes and Ketones 2 1 Allylic trimethoxysilanes are activated by a catalytic combination of CuCl and TBAF 8.2.3.4. Coupling with Organoboron Reagents 8.2.3.4. Coupling with Organoboron Reagents 8.2.3.4. Coupling with Organoboron Reagents 8.2.3.4. Coupling with Organoboron Reagents 8.2.4. Carbonylation Reactions- 1 2 8.2.4. Carbonylation Reactions- 8.2.4.1.-- Hydrocarbonylation 2 1 8.2.4. Carbonylation Reactions 8.2.4.2. Solvocarbonylation 8.2.4.2. Solvocarbonylation 8.2.4.2. Solvocarbonylation 8.4. The Olefin Metathesis Reaction 8.4. The Olefin Metathesis Reaction 8.4. The Olefin Metathesis Reaction 8.4. The Olefin Metathesis Reaction 8.4. The Olefin Metathesis Reaction 8.4. The Olefin Metathesis Reaction Chapter 9 Carbon-Carbon Bond-Forming Reactions of Compounds of Boron, Silicon, and Tin Introduction 9.1. Organoboron Compounds 9.1.1. Synthesis of Organoboranes 9.1.2. Carbonylation and Other One-Carbon Homologation Reactions