中国科学院大学-高等有机化学-第四章-碳-碳多重键的亲电子加成-Electrophilic Additions to Carbon-Carbon Multiple Bonds.ppt

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2021-01-13 发布于湖北
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中国科学院大学-高等有机化学-第四章-碳-碳多重键的亲电子加成-Electrophilic Additions to Carbon-Carbon Multiple Bonds.ppt

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4.5.2. Reactions of Organoboranes 4.5.2. Reactions of Organoboranes 4.5.2. Reactions of Organoboranes 4.5.3. Enantioselective Hydroboration 4.5.3. Enantioselective Hydroboration 4.5.3. Enantioselective Hydroboration 4.5.4. Hydroboration of Alkynes Anti addition Anti elemination 4.6. Hydroalumination, Carboalumination, Hydrozirconation, and Related Reactions 4.6. Hydroalumination, Carboalumination, Hydrozirconation, and Related Reactions 4.6. Hydroalumination, Carboalumination, Hydrozirconation, and Related Reactions Cp2ZrCl2 Cp2ZrCl2 Homework 1, 12,15,17 Introduction 5.1. Addition of Hydrogen at Carbon-Carbon Multiple Bonds 5.1.1. Hydrogenation Using Heterogeneous Catalysts 5.1.2. Hydrogenation Using Homogeneous Catalysts 5.1.2. Hydrogenation Using Homogeneous Catalysts 4.2.1. Halocyclization 4.2.1. Halocyclization more stable trans product was obtained under acidic conditions in which there is acid-catalyzed equilibration (thermodynamic control). Mechanism is under question!!! 4.2.1. Halocyclization I+ is delivered from the same face of carboxylate 4.2.1. Halocyclization or 4.2.2. Sulfenylcyclization and Selenenylcyclization 4.2.2. Sulfenylcyclization and Selenenylcyclization 4.2.3. Cyclization by Mercuric Ion 4.2.3. Cyclization by Mercuric Ion 4.3. Electrophilic Substitution to Carbonyl Groups 4.3.1. Halogenation to Carbonyl Groups NBS, NCS, SOCl2, CF3SO2Cl 4.3.2. Sulfenylation and Selenenylation to Carbonyl Groups 4.4. Additions to Allenes and Alkynes 4.4. Additions to Allenes and Alkynes 4.4. Additions to Allenes and Alkynes 4.5. Addition at Double Bonds via Organoborane Intermediates 4.5.1. Hydroboration 4.5.1. Hydroboration 4.5.1. Hydroboration 4.5.1. Hydroboration 4.5.1. Hydroboration 4.5.1. Hydroboration 4.5.2. Reactions of Organoboranes 4.2.2. Sulfenylcyclization and Selenenylcyclization 4.2.2. Sulfenylcyclization and Selenenylcyclization 4.4. Additions to Allenes and Alkynes 4.4. Additions to Allenes and Alkynes 4.4. Additions to Allenes and Alkynes