中低品位钾长石制备熔块釉及其工艺研究.docVIP

钾长石广泛应用于工业生产，主要用途是制作玻璃和陶瓷等，在材料制备方面的研 究也越来越多。在熔块釉屮，钾长石可供给AI2O3和Sio2,以及碱金属氧化物，既 是瘠性原料,乂是熔剂性原料。我国钾长石资源储量极其丰富,这为钾长石的开发 利用奠定了良好的基础。 陶瓷行业是矿产资源消耗量大、能耗高、污染比较大的行业，在带来巨大经济 效益的同时，也带来了严重的环境问题，同时，优质钾长石资源逐渐枯竭，选矿成 木仍然较高。木研究基于屮低品位钾长石矿的高效开发和利用，以河南南召屮品位 钾长石为主要原料制备了两种低温透明裂纹熔块釉，制备的熔块釉无铅无毒、质量 易控制、烧成范围较宽、受温度变化影响较小，利于缓解当前严重的环境问题以及 陶瓷行业的可持续发展。 论文制备了两种低温透明裂纹熔块釉（高硼熔块釉和低硼熔块釉）制备的最佳 T艺流稈为：按配方分别称取钾长石、氧化钙、硼酸、石英、碳酸钾等原料，在600°C 下预烧4h后,在1100°C熔融,保温6h后水淬；高硼熔块釉中B2O3含量为24.46%, 其釉浆制备的最佳工艺条件为：熔块微粉、水及瓷十?的质量比为1:2:0.05样品，湿 法球磨时间为4舫，陈化时间为72h；制备得到的釉浆的平均粒度为2.500呵，釉烧 温度为870°C?890°C,釉烧保温时间为60mino低硼熔块釉屮B2O3含量为21.41%, 其釉浆制备的最佳T艺条件为：熔块微粉、水及瓷土的质量比为1:2:0.05,湿法球磨 时间为48h,陈化时间为72h；制备得到的釉浆的平均粒度为2.704卩m的釉浆,釉烧 温度为950°C?970°C,釉烧保温时间为60mino 关键词：钾长石；熔块釉；配方；制备丁艺 Abstract Potassium feldspar is widely used in industrial production of chcmicalfcrtiliz- er,ceramic and glass,and the research of preparation in materials also has made a lot of progress in recent years.In frit glaze,potassium feldspar can supply SiO^AbCh andalkali metal oxide,and its non-plastic raw material as well as solve nt raw material.The reserves of potassium feldspar in China is extremely riehjaying a fascinating foundation for the development and utilization of potash feldspar. Ceramic industry,a high pollution industry,consumes lot of mineral and energy rcsourccs.lt brings economic benefits as well as serious environmental problcms.as the same time,the high quality of potassium feldspar mineral resources is drying up and the cost of beneficiation is still high.Based on the the efficient development and utilization of potassium feldspar of low and medium grade,this research prepared two kinds oflow temperature transparent-cracked frit glaze,which is lead-free and non-toxic,easy to control the quality offrit glaze and hard to be aflected by temperature changes,and has wide range of temperature of glaze firing,and its conducive toallcviating the current severe environment problemsand the sustainable development of ceramic industry. This research prepared two kin